首页|宜兴市东北部秋季VOCs污染特征及其影响分析

宜兴市东北部秋季VOCs污染特征及其影响分析

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2022年秋季在宜兴市东北部区域利用大气挥发性有机物(VOCs)快速在线监测系统(TH-300B)对大气VOCs进行连续在线监测,以了解其化学特征,及其对臭氧和二次有机气溶胶的生成影响分析。结果表明:宜兴市东北部区域秋季大气VOCs中平均质量浓度最高的前10种VOCs组分依次为甲苯、间/对二甲苯、二氯甲烷、丙酮、乙酸乙酯、1,2-二氯乙烷、乙烷、氯甲烷、乙烯和乙炔。宜兴市东北部区域秋季VOCs的臭氧生成潜势(ozone formation potential,OFP)贡献最高的前10种VOCs组分中,芳香烃类物质OFPs贡献占比(73。37%)>烯烃类物质OFPs贡献占比(19。24%)>含氧挥发性有机物(OVOCs)类物质OFPs贡献占比(7。39%)。宜兴市东北部区域秋季VOCs的二次有机气溶胶(SOA)生成潜势贡献最高的前10种物种全部是芳香烃类物质。通过特征VOCs组分相关比值分析法,该区域秋季苯和甲苯主要来自工业生产和溶剂涂料排放,丙烯主要来自工业排放,异戊烷和正戊烷主要来自石油和天然气的使用排放。
Chemical Characteristics and Impact Analysis of VOCs in the Northeast Area of Yixing in Autumn
In order to analyze the chemical characteristics and impact analysis of ozone or secondary organic aero-sol formation of VOCs in the northeast area of Yixing,atmospheric Volatile Organic Compounds(VOCs)were continuously monitored via an online GC~FID/MS system during the autumn of 2022.During the sampling peri-od,the top 10 average concentration of atmospheric VOCs was toluene,meta-xylene/para-xylene,dichloromethane,acetone,ethyl acetate,1,2-dichloroethane,ethane,methyl chloride,ethylene and acetylene successively.In the top 10 ozone formation potential of VOCs,aromatic hydrocarbons OFPs contribution proportion(73.37%)>olefin OFPs contribution proportion(19.24%)>oxygenated volatile organic compounds OFPs contribution proportion(7.39%).The top 10 species with the highest contribution of Secondary Organic Aerosol(SOA)generation poten-tial of autumn VOCs in the northeast of Yixing were all aromatic hydrocarbons.According to the analysis meth-ods of correlation ratio of typical VOCs,benzene and toluene were mainly from industrial and solvent emissions.Propylene was mainly from industrial emissions.Isopentane and n-pentane were mainly from petroleum and natu-ral gas emissions in the area.

Volatile Organic Compounds(VOCs)chemical characteristicsOzone Formation Potential(OFP)Secondary Organic Aerosol(SOA)formation potential

王孝明

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上海誉琰科技有限公司,上海 201899

挥发性有机物(VOCs) 污染特征 臭氧生成潜势(OFP) 二次有机气溶胶(SOA)生成潜势

2024

绿色科技
花木盆景杂志社

绿色科技

影响因子:0.365
ISSN:1674-9944
年,卷(期):2024.26(16)