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宜兴市东北部秋季VOCs污染特征及其影响分析

Chemical Characteristics and Impact Analysis of VOCs in the Northeast Area of Yixing in Autumn

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2022年秋季在宜兴市东北部区域利用大气挥发性有机物(VOCs)快速在线监测系统(TH-300B)对大气VOCs进行连续在线监测,以了解其化学特征,及其对臭氧和二次有机气溶胶的生成影响分析.结果表明:宜兴市东北部区域秋季大气VOCs中平均质量浓度最高的前10种VOCs组分依次为甲苯、间/对二甲苯、二氯甲烷、丙酮、乙酸乙酯、1,2-二氯乙烷、乙烷、氯甲烷、乙烯和乙炔.宜兴市东北部区域秋季VOCs的臭氧生成潜势(ozone formation potential,OFP)贡献最高的前10种VOCs组分中,芳香烃类物质OFPs贡献占比(73.37%)>烯烃类物质OFPs贡献占比(19.24%)>含氧挥发性有机物(OVOCs)类物质OFPs贡献占比(7.39%).宜兴市东北部区域秋季VOCs的二次有机气溶胶(SOA)生成潜势贡献最高的前10种物种全部是芳香烃类物质.通过特征VOCs组分相关比值分析法,该区域秋季苯和甲苯主要来自工业生产和溶剂涂料排放,丙烯主要来自工业排放,异戊烷和正戊烷主要来自石油和天然气的使用排放.
In order to analyze the chemical characteristics and impact analysis of ozone or secondary organic aero-sol formation of VOCs in the northeast area of Yixing,atmospheric Volatile Organic Compounds(VOCs)were continuously monitored via an online GC~FID/MS system during the autumn of 2022.During the sampling peri-od,the top 10 average concentration of atmospheric VOCs was toluene,meta-xylene/para-xylene,dichloromethane,acetone,ethyl acetate,1,2-dichloroethane,ethane,methyl chloride,ethylene and acetylene successively.In the top 10 ozone formation potential of VOCs,aromatic hydrocarbons OFPs contribution proportion(73.37%)>olefin OFPs contribution proportion(19.24%)>oxygenated volatile organic compounds OFPs contribution proportion(7.39%).The top 10 species with the highest contribution of Secondary Organic Aerosol(SOA)generation poten-tial of autumn VOCs in the northeast of Yixing were all aromatic hydrocarbons.According to the analysis meth-ods of correlation ratio of typical VOCs,benzene and toluene were mainly from industrial and solvent emissions.Propylene was mainly from industrial emissions.Isopentane and n-pentane were mainly from petroleum and natu-ral gas emissions in the area.

Volatile Organic Compounds(VOCs)chemical characteristicsOzone Formation Potential(OFP)Secondary Organic Aerosol(SOA)formation potential

王孝明

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上海誉琰科技有限公司,上海 201899

挥发性有机物(VOCs) 污染特征 臭氧生成潜势(OFP) 二次有机气溶胶(SOA)生成潜势

2024

绿色科技
花木盆景杂志社

绿色科技

影响因子:0.365
ISSN:1674-9944
年,卷(期):2024.26(16)