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气相分子吸收光谱法测定土壤中氨氮干扰物质影响分析

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探讨了气相分子吸收光谱法测定土壤中氨氮时,硫化物、挥发性有机物、甲醛、乙草胺、丙烯酰胺、尿素等土壤中存在的物质对分析可能存在的影响,提出了干扰物质的去除方法。实验结果表明:硫化物、挥发性有机物、甲醛、乙草胺、丙烯酰胺、尿素对氨氮测定均产生负干扰,以对测定值误差的要求超过±10%来作为干扰的判定标准,则硫化物、挥发性有机物干扰明显,甲醛、乙草胺、丙烯酰胺、尿素干扰较小。土壤提取液中加入1 mL(1+1)盐酸及0。2 mL无水乙醇,加热煮沸2~3 min,可消除硫化物和挥发性有机物的干扰。
Influence Analysis of Interfering Substances in the Determination of Ammonia Nitrogen in Soil by Gas Phase Molecular Absorption Spectrometry
This paper discusses the influence of sulfide,volatile organic compounds,formaldehyde,acetochlor,ac-rylamide and urea on the determination of ammonia nitrogen in soil,and proposes the removal method of interfer-ing substances.Experimental results show that sulfide,volatile organic compounds,formaldehyde,acetochlor,ac-rylamide and urea all have negative interference on the determination of ammonia nitrogen.If the error of the de-termination value is more than+10%,the interference of sulfide and volatile organic compounds is obvious,while the interference of formaldehyde,acetochlor,acrylamide and urea is small.Adding 1ml(1+1)hydrochloric acid and 0.2ml anhydrous ethanol into the soil extract solution,heating and boiling for 2~3 min,can eliminate the interference of sulfides and volatile organic compounds.

gas phase molecular absorption spectroscopysoilammonia nitrogeninterferenceelimination

杨登、王卉、陈英、杨海荣

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湖北省生态环境厅恩施州生态环境监测中心,湖北恩施 445000

恩施市环境监测站,湖北恩施 445000

气相分子吸收光谱法 土壤 氨氮 干扰 消除

2024

绿色科技
花木盆景杂志社

绿色科技

影响因子:0.365
ISSN:1674-9944
年,卷(期):2024.26(18)