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脱硫洗涤塔双相不锈钢焊接特性研究

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针对脱硫洗涤塔的超级双相不锈钢的焊接工艺进行了深入研究,通过实验研究焊接热输入及焊接速率等对焊缝金属的宏观和微观构造、力学性能以及抗腐蚀能力有关的研究,优选最佳的合金材料。试验表明:当采用钨极氩弧焊的焊接方式,并且保证热输入在0。3~1。5 kJ/mm,层间温度控制在150 ℃以内,焊接所采用的材料为实心TIG焊丝25。10。4 L以及焊条25。10。4 LR,保护气体选用由98%的氩粒子密度和2%的氮粒子密度构成的混合气体时,焊接接头的表观状况优秀,无明显的缺点。焊缝的微观结构表明母材是轧制形态,而奥氏体以条纹的形式规则分布在铁素体基底上。焊缝的硬度大约是300,特别是热影响区域(HAZ)的硬度最高可以达到330。焊缝的冲击韧度在110~140 J/cm2,表面没有形成点蚀蚀坑,而且其腐蚀速度小于10 mdd。在含有氯和硫酸根离子的40 ℃环境中,焊接接头依旧表现出一定的抗点蚀性能。
Research on Welding Characteristics of Duplex Stainless Steel in Desulfurization Washing Towers
This paper focuses on the welding process of super duplex stainless steel for desulfurization washing towers.Through experimental research on the effects of welding heat input and welding rate on the macroscopic and microscopic structure,mechanical properties,and corrosion resistance of the weld metal,the optimal alloy material is selected.Results have shown that when using tungsten inert gas welding,ensuring a heat input within the range of 0.3~1.5 kJ/mm,controlling the interlayer temperature within 150 ℃,solid TIG welding wire 25.10.4 L and welding rod 25.10.4 LR,using a mixed gas composed of 98%argon particle density and 2%nitro-gen particle density,the apparent condition of the welded joint is excellent without obvious defects.The micro-structure of the weld indicates that the base metal is in a rolled form,while austenite is regularly distributed on the ferrite substrate in the form of stripes.The hardness of the weld seam is approximately 300,especially the hard-ness of the heat affected zone(HAZ)can reach up to 330.The impact toughness of the weld seam is between 110-140 J/cm2.There is no pitting on the surface,and its corrosion rate is less than 10mdd.In a 40℃ environment containing chloride and sulfate ions,welded joints still exhibit certain resistance to pitting corrosion.

desulfurization washing towerssuper duplex stainless steelweldingmechanical propertiespitting

胡兴雷、李晓波、李珂、申博涵

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中国船舶集团有限公司第七一一研究所,上海 200090

脱硫洗涤塔 超级双相不锈钢 焊接 热力学性能 点蚀

2024

绿色科技
花木盆景杂志社

绿色科技

影响因子:0.365
ISSN:1674-9944
年,卷(期):2024.26(18)