首页|石家庄市某大学校园VOCs污染特征与源解析

石家庄市某大学校园VOCs污染特征与源解析

扫码查看
为研究石家庄市裕华区某大学校园挥发性有机物(VOCs)的污染特征,明晰VOCs来源,利用SUMMA罐、气相色谱质谱联用仪(GC-MS)离线监测2024年5月中校园内的55种VOCs,分析VOCs的浓度分布与组成特征,计算其O3生成潜势(OFP)及二次有机气溶胶生成潜势(SOAP)。结果表明:监测期间,石家庄市某大学校园TVOCs(总VOCs)平均浓度为221。19 μg/m3,组分占比比较为:卤代烃>OVOCs>芳香烃>烷烃>烯烃>含硫化合物,芳香烃与OVOCs的OFP贡献率最高,削减机动车排放与溶剂使用是控制O3污染的关键。萘、1,2,4-三甲苯、1,3,5-三甲苯、对二甲苯和甲苯对SOAP贡献率较高,控制苯系物的排放是降低SOA生成的关键。通过源解析及监测数据分析,得出动车尾气排放是主要贡献源,其次为农药源,氯乙烷、邻二氯苯等烷烃及苯系物为优势贡献物种,因此机动车尾气排放控制为校园内VOCs管控的重点。
Characteristics and Source Analysis of VOCs Pollution in a University Campus in Shijiazhuang City
In order to study the characteristics of VOCs pollution in a university campus in Yuhua District of Shi-jiazhuang City and identify the sources of VOCs,55 VOCs on campus in mid-May 2024 were monitored offline by SUMMA canister and Gas Chromatography Mass Spectrometry(GC-MS),and the concentration distribution and composition characteristics of VOCs were analyzed.O3 generation potential(OFP)and Secondary Organic Aerosol generation Potential(SOAP)were calculated.The results show that:During the monitoring period,the average concentration of TVOCs(Total VOCs)in a university campus in Hebei city was 221.19 μg/m3,and the proportion of components was in the order of halogenated hydrocarbons>OVOCs>aromatics>alkanes>olefins>sulfur-containing compounds.The OFP contribution rate of aromatic hydrocarbons and OVOCs is the highest.Re-ducing vehicle emission and flux use is the key to control O3 pollution.Naphthalene,1,2,4-tritylene,1,3,5-trity-lene,paraxylene and toluene have a high contribution rate to SOAP.Controlling the emission of benzene series is the key to reduce the generation of SOA.Through source analysis and monitoring data analysis,it is found that vehicle exhaust emissions are the main contributing source.Pesticide sources,chloroethane,o-dichlorobenzene and other alkane and benzene series are the dominant contributing species.Therefore,vehicle exhaust emission control is the focus of VOCs management and control on campus.

VOCscampusemission characteristicssource analysisShijiazhuang City

刘佳悦、刘大喜、崔建升

展开 >

河北科技大学 环境科学与工程学院,河北 石家庄 050018

河北省污染防治生物技术实验室,河北 石家庄 050018

VOCs 校园 排放特征 源解析 石家庄市

2024

绿色科技
花木盆景杂志社

绿色科技

影响因子:0.365
ISSN:1674-9944
年,卷(期):2024.26(22)