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用于甲烷裂解制氢的气体分散系统实验研究

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甲烷气体直接通入高温熔融介质中,不仅甲烷气体在熔融介质中难以均匀分散,而且所形成气泡的尺寸相对较大,不利于甲烷气体与高温熔融介质之间的热交换,进而影响甲烷裂解制氢效率。鉴于此,本文提出了一种气体分散系统装置,通过采用微孔陶瓷作为气体分散器,不但能够大大提升气体在熔融介质中的分散程度,而且可有效减小气泡尺寸。针对该气体分散系统装置,开展了冷态实验以探究微孔陶瓷的孔径、外径及进气流量等参数对气体分散效果的影响规律。结果表明:当微孔孔径处于50~100 μm时,不但气泡尺寸相对较小,而且气体压降相对较低;微孔陶瓷的外径过大或过小均不利于增强气体的分散效果;适度提高进气流量可在一定程度上促进气液之间的相互作用。
Experimental Study on Gas Dispersion Systems for Hydrogen Production by Methane Pyrolysis
When methane gas is directly introduced into the liquid molten medium,it is difficult to be uniformly dispersed in the liquid molten medium,and the formed bubble size is relatively large.This is not conducive to the heat exchange between methane gas and the high-temperature molten medium,thereby affecting the efficiency of hydrogen production by methane pyrolysis.In view of this,a gas dispersion system device is proposed.By using microporous ceramics as the gas disperser,it can not only greatly improve the dispersion degree of the gas in the liquid molten medium,but also effectively reduce the bubble size.Cold-state experiments were carried out on this gas dispersion system device to explore the influence of parameters such as the pore size,outer diameter of the microporous ceramics,and inlet gas flow rate on the gas dispersion effect.The results show that when the micro-pore size is within the range of 50~100 μm,not only the bubble size is relatively small,but also the resulting gas pressure drop is relatively low;both an overly large or small outer diameter of the microporous ceramics is not conducive to enhancing the gas dispersion effect;moderately increasing the inlet gas flow rate can promote the in-teraction between the gas and the liquid to a certain extent.

methane pyrolysis for hydrogen productiongas dispersion systemsmicroporous ceramicmolten metal

王建维、胡兴雷、李珂、沈腾、李晓波

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中国船舶集团有限公司 第七一一研究所,上海 200090

甲烷裂解制氢 气体分散系统 微孔陶瓷 熔融金属

2024

绿色科技
花木盆景杂志社

绿色科技

影响因子:0.365
ISSN:1674-9944
年,卷(期):2024.26(22)