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半干法硫铁矿制酸装置

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半干法制酸是让转化后的气体跨过恒浓点,用吸湿塔来减少气体中水分.吸湿塔不加水、不串酸,循环酸浓度不变,通过控制水硫比和上塔酸温来维持循环酸浓度,填料中表面冷凝与吸收并行.由气体带进塔的水为全域水,气体带水1 t可产约5 t蒸汽.吨酸产汽量0.93 t,其中中压过热蒸汽0.35 t、低压饱和蒸汽0.58 t,若全产低压蒸汽则达1.02 t.可实现零循环水和尾吸塔稀酸零排放.半干法制酸工艺腐蚀性小,接近干法制酸的极限,看似不加水的酸热回收工艺,且比酸热回收工艺更安全.吸湿塔进气中的SO3成酸率超过70%,成酸热相当于气体190℃温升,操作负荷可降至30%,或进塔气体的φ(SO2)低至3%.
Semi-dry sulphuric acid plant from pyrite
The semi-dry sulphuric acid process lets the converted gas to leap over the identical concentration point and using a moisture absorption tower to reduce water in the gas.It does not add water or crossflow acid,and the circulating acid concentration remains unchanged in the tower.The circulating acid concentration is maintained by controlling the water-sulphur ratio and the inlet acid temperature.The surface condensation and absorption in the packing are parallel.The water in the gas is the whole area water for the process,and it can produce about 5 tons of steam for per ton of water.The steam yield per ton of production acid is 0.93 tons,including 0.35 tons of medium pressure superheated steam and 0.58 tons of low pressure saturated steam.If all low pressure steam is produced,it will reach 1.02 tons.It can achieve zero cooling water and zero discharge of weak acid from tail suction tower.The semi-dry acid process has low corrosiveness and is the limit of dry acid production.It appears to be an acid heat recovery process without adding water,and is safer than the acid heat recovery process.The acid formation rate from SO3 in the gas at inlet the moisture absorption tower exceeds 70%,and the heat of acid formation is equivalent to a gas temperature rise of 190℃.The operating load can be reduced to 30%,or the SO2 gas strength into the plant is as low as 3%.

semi-dry sulphuric acid processpyrite-based sulphuric acidmoisture absorption towersteam yieldacid heat recoverysulphuric acid plant

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兴化宏伟科技有限公司,江苏泰州 225715

半干法 硫铁矿制酸 吸湿塔 蒸汽产率 酸热回收 硫酸装置

2024

硫酸工业
南化集团研究院,全国硫酸工业信息站

硫酸工业

影响因子:0.308
ISSN:1002-1507
年,卷(期):2024.(1)
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