Methanol steam reforming for hydrogen production driven by an atomically precise Cu catalyst

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外文摘要：Plasmon-induced hot-electron transfer from metal nanostructures is being intensely pursed in current photocatalytic research,however it remains elusive whether molecular-like metal clusters with excitonic behavior can be used as light-harvesting materials in solar energy utili-zation such as photocatalytic methanol steam reforming.In this work,we report an atomically precise Cu13 cluster protected by dual ligands of thiolate and phosphine that can be viewed as the assembly of one top Cu atom and three Cu4 tetrahedra.The Cu13H10(SR)3(PR'3)7(SR=2,4-dichlorobenzenethiol,PR'3=P(4-FC6H4)3)cluster can give rise to highly efficient light-driven activity for methanol steam reforming toward H2 production.

外文关键词：

NanoclusterPhotocatalysisMethanol steam reformingAtomically preciseCopper catalyst

作者：

Weigang Hu、Haoqi Liu、Yuankun Zhang、Jiawei Ji、Guangjun Li、Xiao Cai、Xu Liu、Wen Wu Xu、Weiping Ding、Yan Zhu

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作者单位：

School of Chemistry and Chemical Engineering,Nanjing University,Nanjing,210093,China

School of Physical Science and Technology,Ningbo University,Ningbo,315211,China

基金：

国家自然科学基金国家自然科学基金国家自然科学基金江苏省自然科学基金

项目编号：

221252022193200422101128BK20220033

出版年：

2024

DOI：

10.1016/j.gee.2023.12.004

绿色能源与环境(英文)

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ISSN：

年,卷(期)：2024.9(7)