首页|Facile synthesis of accordion-like porous carbon from waste PET bottles-based MIL-53(Al)and its application for high-performance Zn-ion capacitor

Facile synthesis of accordion-like porous carbon from waste PET bottles-based MIL-53(Al)and its application for high-performance Zn-ion capacitor

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It is of great scientific and economic value to recycle waste poly(ethylene terephthalate)(PET)into high-value PET-based metal organic frameworks(MOFs)and further convert it into porous carbon for green energy storage applications.In the present study,a facile and cost-effective hydrothermal process was developed to direct recycle waste PET bottles into MIL-53(Al)with a 100%conversation,then the MOF-derived porous carbon was assembled into electrodes for high-performance supercapacitors.The results indicated that the as-synthesized carbon exhibited high SSA of 1712 m2 g-1 and unique accordion-like structure with hierarchical porosity.Benefit to these advantageous characters,the assembled three-electrode supercapacitor displayed high specific capacitances of 391 F g-1 at the current density of 0.5 A g-1 and good rate capability of 73.6%capacitance retention at 20 A g-1 in 6 mol L-1 KOH electrolyte.Furthermore,the assembled zinc ion capacitor still revealed outstanding capacitance of 335 F g-1 at 0.1 A g-1,excellent cycling stability of 92.2%capacitance retention after 10 000 cycles and ultra-high energy density of 150.3 Wh kg-1 at power density of 90 W kg-1 in 3 mol L-1 ZnSO4 electrolyte.It is believed that the current work provides a facile and effective strategy to recycle PET waste into high-valuable MOF,and further expands the applications of MOF-derived carbons for high-performance energy storage devices,so it is conducive to both pollution alleviation and sustainable economic development.

PETRecyclingPorous carbonSupercapacitorEnergy storage

Jiaxin Li、Shuai Zhang、Yumeng Hua、Yichao Lin、Xin Wen、Ewa Mijowska、Tao Tang、Xuecheng Chen、Rodney S.Ruoff

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Faculty of Chemical Technology and Engineering,West Pomeranian University of Technology,Piastów Ave.42,71-065,Szczecin,Poland

Key State Key Laboratory of Polymer Physics and Chemistry,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun,130022,China

School of Safety Engineering,China University of Mining and Technology,Xuzhou,221116,China

Institute of Advanced Electrical Materials,Qingdao University of Science and Technology,Qingdao,266042,China

Institute for Basic Science Center for Multiple Dimensional Carbon Materials,Ulsan,44919,Republic of Korea

Department of Chemistry,Ulsan National Institute of Science and Technology(UNIST),Ulsan,44919,Republic of Korea

Department of Materials Science and Engineering,Ulsan National Institute of Science and Technology(UNIST),Ulsan,44919,Republic of Korea

School of Energy and Chemical Engineering,Ulsan National Institute of Science and Technology(UNIST),Ulsan,44919,Republic of Korea

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NCN,PolandNAWAInstitute for Basic Science

UMO-2020/39/B/ST8/029372020 PPN/BEK/2020/1/00129/ZAS/00001IBS-R019-D1

2024

10.1016/j.gee.2023.01.002

绿色能源与环境(英文)

绿色能源与环境(英文)

CSTPCD
ISSN：
年,卷(期)：2024.9(7)