首页|气相色谱-质谱联用仪测定生干黑芝麻及芝麻油中脂肪酸组成的研究

气相色谱-质谱联用仪测定生干黑芝麻及芝麻油中脂肪酸组成的研究

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本研究采用异辛烷作为脂肪酸的提取剂,甲醇钠-甲醇作为甲酯化试剂,然后通过气相色谱-质谱联用技术建立Q1-SIM方法,旨在对脂肪酸进行定性和定量分析,从而探索生干黑芝麻及芝麻油中的脂肪酸组成.结果表明:生干黑芝麻和芝麻油中共检测到17种脂肪酸,主要包括C16∶0、C18∶0、C18∶1N9C和C18∶2N6C.此外,我们还发现了 5种鲜有报道的脂肪酸成分:C17∶1、C18∶1N9T、C21∶0、C20∶4N6、C20∶5N3,在生干黑芝麻油脂和芝麻油中含量分别为0.019%、0.056%、0.011%、0.013%、0.045%和 0.027%、0.112%、0.010%、0.011%、0.052%.
The study of fatty acid composition in raw and dry black sesame and sesame oil by GC-MS
In this study,isooctane was used as fatty acid extraction agent,sodium methanol-methanol as methyl esterification reagent,and then Q1-SIM method was established by gas chromatography-mass spectrometry,aiming to make qualitative and quantitative analysis of fat-ty acids,so as to explore the fatty acid composition in raw and dry black sesame and sesame oil.The experimental results showed that a total of 17 fatty acids were detected in raw and dry black sesame and sesame oil,mainly including C16∶0,C18∶0,C18∶1N9C and C18∶2N6C.In addi-tion,we also found five rarely reported fatty acid components:C17∶1,C18∶1N9T,C21∶0,C20∶4N6,C20∶5N3,which contained 0.019%,0.056%,0.011%,0.013%,0.045%in raw and dry black sesame oil and 0.027%,0.112%,0.010%,0.011%,0.052%in sesame oil,re-spectively.

GC-MSraw and dry black sesamesesame oilfatty acids

慕妮、杨俊、周易枚、胡雨、王恺、石敏、Fan Qingqing

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南通市食品药品监督检验中心(南通 226000)

气相色谱-质谱法 生干黑芝麻 芝麻油 脂肪酸

江苏省南通市社会民生科技计划项目(指导性)

MSZ2022179

2024

粮食与食品工业
国家粮食储备局无锡科研设计院 中国粮油学会

粮食与食品工业

影响因子:0.503
ISSN:1672-5026
年,卷(期):2024.31(4)