首页|生物质氧化石墨烯基双网络水凝胶球的制备与吸附性能

生物质氧化石墨烯基双网络水凝胶球的制备与吸附性能

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为了减轻废弃甘蔗渣给环境带来的压力,以废弃甘蔗渣为原料,制备了生物质氧化石墨烯(BGO).以Ca2+交联的海藻酸钠(SA)为第一交联网络,以BGO为异质晶核,借助于冷冻-解冻法诱导聚乙烯醇(PVA)结晶交联,制备了 PVA/SA/BGO双网络水凝胶球,考察了 PVA/SA/BGO双网络水凝胶球的结构、形貌以及对有机染料结晶紫(Cv)的吸附性能.结果表明:所得BGO具有片层结构和丰富的含氧基团.PVA/SA/BGO双网络水凝胶球对CV的最大吸附容量为460.21 mg·g-1,吸附过程符合Langmuir等温吸附模型和拟二级动力学吸附模型.
Preparation and Adsorption Properties of Biomass Graphene Oxide-based Double Network Hydrogel Spheres
In order to alleviate the enormous pressure that waste bagasse puts on the environment,BGO was prepared from waste bagasse.With Ca2+crosslinked SA as the first network and BGO as the heterogeneous nucleus for the second network,the PVA/SA/BGO double-network hydrogel spheres were constructed with the help of freeze-thaw method.The structure,morphology and adsorption properties of the PVA/SA/BGO double-network hydrogel for the organic dye crystalline violet(CV)were investigated.The results show that the obtained BGO has a lamellar structure and abundant oxygen-containing groups.The maximum adsorption amount of PVA/SA/BGO double-network hydrogel toward CV is 460.21 mg·g-1,and the adsorption process is in accordance with the Langmuir adsorption model and the pseudo-second-order kinetics model.

bagassebiomass graphenedye adsorptiondouble network hydrogel

盛延云、曾宁宁、王倩杰、刘红宇、潘炳力

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河南科技大学动物科技学院,河南洛阳 471023

河南科技大学化学化工学院,河南洛阳 471023

甘蔗渣 生物质石墨烯 染料吸附 双网络水凝胶

国家自然科学基金项目国家自然科学基金项目

2217505751675162

2024

河南科技大学学报(自然科学版)
河南科技大学

河南科技大学学报(自然科学版)

CSTPCD北大核心
影响因子:0.673
ISSN:1672-6871
年,卷(期):2024.45(4)