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聚乙二醇木材复合相变储能材料的制备及表征

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以木材为骨架,聚乙二醇-10000为相变基元,通过木材的毛细管吸收效应,物理吸附聚乙二醇-10000,制备聚乙二醇木材复合相变储能材料.通过傅里叶变换红外( FTIR)谱图分析官能团,扫描电子显微镜(SEM)分析微观形貌,X射线衍射(XRD)分析结晶度,可知木材与聚乙二醇能很好的相互结合,并且随着聚乙二醇- 10000含量的增加,聚乙二醇木材复合相变储能材料结晶度逐渐增加;通过差示扫描量热( DSC)以及热重(TG)分析可知,聚乙二醇木材复合相变储能材料的相变焓先增加后减少,最大相变焓值为43.22 J·g-1,热稳定性明显增加;聚乙二醇的无水乙醇溶液对木材渗透性的研究表明,木材吸附聚乙二醇主要为抛物线状三段式吸收.
Preparation and Characterization of Polyethylene Glycol Wood Composite Phase Change Materials
Through capillary adsorption effect of wood with physical adsorption of polyethylene glycol ( PEG )-10000, polyethylene glycol wood composite phase change materials( PCM) was prepared with wood as skeleton, and polyethylene glycol-10000( PEG-10000) as phase transformation unit. Functional groups were analyzed by fourier transform infrared ( FTIR) spectra, microscopic morphology was analyzed by scanning electron microscopy ( SEM ) and degree of crystallinity was analyzed by X-ray diffraction ( XRD) , it is concluded that wood was well combined with PEG and the degree of crystallinity of PCM increased gradually with PEG-10000 content going up. By using differential scanning calorimetry ( DSC) and thermogravimetry ( TG ) analysis, the enthalpy of phase change was first increased and then decreased, the largest phase change enthalpy is 43. 22 J·g-1 and the thermal stability was obviously increased. The study of permeability of PEG ethanol solution to wood shows that PEG adsorption of wood was mainly parabolic three-stage absorption.

poplarpolyethylene glycolphase change enthalpyphase change materialthermal stability

谢成、刘志明、吴鹏、王海英、孟围

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东北林业大学材料科学与工程学院 生物质材料科学与技术教育部重点实验室 哈尔滨150040

东北林业大学林学院 哈尔滨150040

杨木 聚乙二醇 相变焓 相变储能材料 热稳定性

国家自然科学基金人力资源和社会保障部留学回国人员科技活动择优资助项目东北林业大学研究生论文资助项目

3107063307041311401ST1P10

2012

林业科学
中国林学会

林业科学

CSTPCDCSCD北大核心
影响因子:1.272
ISSN:1001-7488
年,卷(期):2012.48(9)
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