首页|Q355B钢精炼过程中非金属夹杂物的演变及分析

Q355B钢精炼过程中非金属夹杂物的演变及分析

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为进一步探究Q355B钢精炼过程中非金属夹杂物的形成与演变规律,在重庆钢铁炼钢厂"BOF→LF→RH→钙处理→CC"工艺生产Q355B钢精炼全流程进行了两炉取样,分析检测了钢液和炉渣成分,揭示了不同阶段非金属夹杂物的形貌和成分演变特征.研究结果表明,Q355B钢精炼过程中的非金属夹杂物主要是SiO2-MnO-Al2O3-TiOx类和CaO-MgO-Al2O3类.SiO2-MnO-Al2O3-TiOx类非金属夹杂物的演变比较复杂,LF造渣精炼过程中加入铝渣球会改性SiO2-MnO-Al2O3类夹杂物为SiO2-MnO-Al2O3-TiOx类,RH钛合金化会改性成为高钛含量Al2O3-TiOx、CaO-Al2O3-TiOx和MnO-Al2O3-TiOx类非金属夹杂物;CaO-MgO-Al2O3类非金属夹杂物几乎在精炼全过程均出现.随着精炼过程中LF造渣精炼、钢包吹氩、RH真空精炼、钙处理和软吹氩搅拌,CaO-MgO-Al2O3类非金属夹杂物从高熔点逐渐向低熔点转变,进入液相区,尺寸和数量逐渐减少.LF精炼使用铝渣球造渣和RH的钛合金化工艺是钢液和渣中钛成分的主要来源,影响Q355B钢精炼过程非金属夹杂物的演变,需进行工艺审视.
Evolution and analysis of non-metallic inclusions during the refining process of Q355B steel
To further investigate the formation and evolution of non-metallic inclusions during the refining process of Q355B steel,two furnace samples were taken from the entire refining process of Q355B steel produced by the"BOF→LF→RH→Calcium treatment→CC"process at Chongqing Iron and Steel Works.The composition of the steel liq-uid and slag was analyzed and tested,revealing the morphology and compositional evolution characteristics of non-metallic inclusions at different stages.The research results indicate that the non-metallic inclusions in Q355B steel during the refining process are mainly SiO2-MnO-Al2O3-TiOx and CaO-MgO-Al2O3 types.The evolution of SiO2-MnO-Al2O3-TiOx type non-metallic inclusions is relatively complex.Adding aluminum slag balls during LF slag re-fining process will modify SiO2-MnO-Al2O3 type inclusions into SiO2-MnO-Al2O3-TiOx type,while RH titanium al-loying will modify them into high Ti content Al2O3-TiOx,CaO-Al2O3-TiOx,and MnO-Al2O3-TiOx type non-metal-lic inclusions.CaO-MgO-Al2O3 type non-metallic inclusions almost appear throughout the refining process.With LF slag refining,ladle argon blowing,RH vacuum refining,calcium treatment,and soft argon stirring during the refi-ning process,CaO-MgO-Al2O3 type non-metallic inclusions gradually transition from high melting point to low melt-ing point,enter the liquid phase zone,and their size and quantity gradually decrease.The use of aluminum slag ball slagging and RH titanium alloying process in LF refining is the main source of titanium composition in steel liquid and slag,which affects the evolution of non-metallic inclusions in Q355B steel refining process and requires process review.

Q355Baluminum slag balltitanium alloyingnonmetallic inclusionrefining process

刘晓峰、申文君、陈露涛、成国光

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重庆钢铁股份有限公司炼钢厂,重庆 401258

北京科技大学绿色低碳钢铁冶金全国重点实验室,北京 100083

Q355B钢 铝渣球 钛合金化 非金属夹杂物 精炼过程

2024

连铸
中国金属学会

连铸

北大核心
影响因子:0.559
ISSN:1005-4006
年,卷(期):2024.(3)
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