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矿用电缆护套热降解动力学与火灾危险性探究

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针对矿用电缆护套的燃烧性能,为电缆安全设计和合理选用提供依据,通过TGA/DSC和CONE探究了MYQ、MHYV和MKVV型电缆护套热降解特性和火灾危险性.结果表明:3 种护套的热降解过程均可分为3 个阶段,热失重主要发生在前 2 个阶段,且第一阶段的失重率最大;MYQ护套受温度影响最大,但是热解过程最缓慢;MHYV和MKVV护套受温度影响较小,但是热解反应最剧烈,且 2 种护套热解过程相似.MYQ护套的火灾危险性远大于MHYV和MKVV护套.根据计算得出的3 种电缆护套的热解活化能,采用广义主图法确定了每种护套各个阶段的热解反应模型.研究结果可为电缆护套材料热解和火灾危险性研究以及电缆护套安全设计提供参考.
Study on Thermal Degradation Kinetics and Fire Hazard of Mine Cable Sheaths
In order to understand the combustion performance of the mine cable sheath and provide the basis for the safe design and reasonable selection of the cable,the thermal degradation characteristics and fire hazard of MYQ,MHYV and MKVV-type cable sheaths are studied by TGA/DSC and CONE experiment respectively.The results show that the thermal degradation process of the three types of sheaths can be divided into three stages,and the thermal weightlessness mainly occurs in the first two stages,and the weightlessness rate of the first stage is the highest.The MYQ-type sheath is the most affected by temperature,but the pyrolysis process is the slowest.The MHYV and MKVV-type sheaths are less affected by temperature,but the pyrolysis reaction is the most in-tense,and the pyrolysis process of the two types of sheaths is similar.The fire risk of MYQ-type sheath is much more than MHYV and MKVV-type sheaths.According to the calculated activation energy of pyrolysis of three types of cable sheaths,the pyrolysis reaction models of each stage for each of the sheaths are determined by the generalized master diagram method.This study can provide a reference for the study of pyrolysis and fire hazard of cable sheath materials and their safe design.

cable sheaththermal decomposition kineticsreaction mechanismfire hazard

袁树杰、侯芳

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安徽理工大学 安全科学与工程学院,安徽 淮南 232001

电缆护套 热解动力学 反应机理 火灾危险性

安徽理工大学研究生创新基金

2021CX2018

2024

兰州工业学院学报
兰州工业学院

兰州工业学院学报

影响因子:0.205
ISSN:1009-2269
年,卷(期):2024.31(1)
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