首页|聚酰胺-胺树形大分子吸附分离材料的构筑及应用研究进展

聚酰胺-胺树形大分子吸附分离材料的构筑及应用研究进展

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聚酰胺-胺(PAMAM)树形大分子具有高度支化的分子结构和丰富的叔胺、酰胺和氨基等功能基团,且各功能基团随树形大分子代数增加呈规律性增加和排布,为吸附位点的集中、层次性分布提供了理想的模板.同时,PAMAM树形大分子具有良好的水溶性、稳定性和pH响应性,可通过调控树形大分子的代数、中心核、外层端基以及溶液pH等提升其对不同水体环境的适应性及对目标物的选择性吸附分离性能,因此,以PAMAM树形大分子构筑吸附分离材料在金属离子、染料、生物分子和药物分子以及CO2的吸附分离领域具有重要应用.本文对PAMAM树形大分子吸附分离材料的构筑及应用研究进展进行了全面总结,并展望了该类材料未来的应用前景和发展方向.
Progress on Fabrication of Polyamidoamine Dendrimer-Based Adsorbents and Their Application
Polyamidoamine(PAMAM)dendrimers are hyperbranched structures and contain abundant functional groups such as tertiary amines,amides and amines groups.The content of the functional groups of PAMAM dendrimer is enhanced following the increase of the generation of dendrimers.The functional groups are arranged regularly within the dendrimer structure,thus providing an ideal template for the concentrated and hierarchical distribution of adsorption sites.Meanwhile,PAMAM dendrimers exhibit excellent water solubility,stability and pH-responsive property.The adaptability to different water environments and selective adsorption properties of PAMAM dendrimers for the target pollutants can be improved by regulating the dendrimer generations,central core,terminal groups and solution pH.Therefore,it is importance of the fabrication of PAMAM dendrimer-based adsorbents for the adsorption and separation of metal ions,dyes,biomacromolecule and drug molecules and CO2.Here,the construction and application of PAMAM dendrimer-based adsorbents were summarized.The future application prospects and development directions were proposed.

PAMAM dendrimersFabricationAdsorptionApplication

刘同河、王柄翔、吴开彦、汪佳璇、牛余忠

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鲁东大学化学与材料科学学院,烟台 264025

PAMAM树形大分子 构筑 吸附 应用

国家自然科学基金山东省高等学校青年创新团队人才引育计划烟台市科技创新发展计划基础研究类重点项目

222782012022JCYJ030

2024

离子交换与吸附
南开大学

离子交换与吸附

CSTPCD
影响因子:0.515
ISSN:1001-5493
年,卷(期):2024.40(1)
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