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含环糊精吸附剂的合成与应用

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环糊精是直链淀粉在酶作用下水解生成的无毒、天然、廉价的环状低聚糖,其疏水空腔可以通过主客体作用包覆污染物中的疏水分子,尤其是芳香类分子,从而提高其吸附效率和吸附选择性.采用环糊精直接和交联剂反应或者采用环糊精对吸附剂进行修饰,可以得到含有环糊精的吸附剂.含有环糊精的吸附剂在吸附分离等领域有广阔的应用前景.文章综述了近年来环糊精在吸附分离材料方面的研究进展,总结了含环糊精吸附剂的不同合成方法;并针对含环糊精吸附剂对有机分子、重金属离子及有机染料等污染物的吸附特点进行分类和探讨;最后对含环糊精吸附剂的未来发展方向进行展望,旨在引起研究者对含有环糊精吸附剂的研究兴趣,并为其提供一些新的启发和思路.
Synthesis and Application of Adsorbents Containing Cyclodextrins
Cyclodextrins(CDs)are derived from the enzymatic hydrolysis of starch,CDs are nontoxic,natural and inexpensive torus-shaped cyclic oligosaccharides.The interior cavity of the CD molecule is hydrophobic,which could trap aromatic contaminants through the host-guest and hydrophobic interaction to improve the adsorption efficiency and selectivity.Adsorbents containing cyclodextrins can be synthesized by the direct reaction of cyclodextrin and crosslinker or by the modification of the adsorbents using cyclodextrin.Adsorbents containing cyclodextrins have important applications in the fields of adsorption and separation.This review focuses on the research progress of adsorbents containing cyclodextrins in recent years.Different methods of the synthesis of adsorbents containing cyclodextrins are also summarized,and the adsorption characteristics of adsorbents containing cyclodextrins for organic molecules,heavy metal ions and organic dyes are classified and discussed too.Finally,the outlook on the future development of adsorbents containing cyclodextrins is presented.We hope that,this paper can arouse the interest of researchers to the study of adsorbents containing cyclodextrins,and provide some inspiration and new ideas for readers.

CyclodextrinAdsorbentOrganic moleculesAdsorption

金秋、王霄鹏、王丽霞、袁金颖

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河南农业大学理学院,郑州 450002

清华大学化学系,北京 100084

环糊精 吸附剂 有机分子 吸附

2024

离子交换与吸附
南开大学

离子交换与吸附

CSTPCD
影响因子:0.515
ISSN:1001-5493
年,卷(期):2024.40(4)