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柠檬酸离子液体脱除汽油中的碱性氮化物

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合成了 N-甲基吡咯烷酮柠檬酸盐离子液体,通过表征表明,反应产物结构与设想合成产物结构一致.使用合成的离子液体催化剂对喹啉模拟汽油进行碱性氮脱除反应,考察不同反应条件下对碱性氮脱除率的影响,确定碱性氮脱除反应最佳工艺条件.实验结果表明,工艺条件条件为60 ℃、40min、剂油比1∶10时碱性氮脱除效果最佳,可达96.94%.在重复回收使用4次后碱性氮脱除率仍可达71.85%,碱性氮脱除效果较好.
Citric Acid Ionic Liquid Removes Alkaline Nitrides from Simulated Oil
N-methylpyrrolidone citrate ionic liquid has been synthesized in this paper.The structure of the reaction product is consistent with that of the proposed synthetic product.The effects of different reaction conditions on the removal rate of basic nitrogen in quinoline simulated gasoline were investigated and the optimum process conditions were determined.The experimental results showed that the removal effect of alkaline nitrogen was the best when the process conditions were 60℃,40 min and the ratio of agent to oil was 1∶10,up to 96.94%.After repeated recycling for 4 times,the removal rate of basic nitrogen can still reach 71.85%,and the removal effect of basic nitrogen is good.

ionic liquidbasbasic nitrogendenitrification reactioncitric acidquinoline simulated oil

刘宇新、罗资琴、朱广进、闫锋、吴田甜

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辽宁石油化工大学石油化工学院,辽宁抚顺 113001

兰州石化职业技术大学石油化学工程学院,甘肃兰州 730060

离子液体 碱性氮 脱氮反应 柠檬酸 喹啉模拟汽油

国家科技重大专项课题

2016ZX05010-004-005

2024

兰州石化职业技术学院学报
兰州石化职业技术学院

兰州石化职业技术学院学报

影响因子:0.224
ISSN:1671-4067
年,卷(期):2024.24(2)