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蒸馏-色谱法分析煤焦油中萘含量的研究

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煤焦油中萘含量是焦油出厂检验的一个重要指标,针对色谱法分析煤焦油中萘含量时会堵塞色谱柱的问题,研究了用蒸馏-色谱法分析煤焦油中萘含量.采用自制的煤焦油蒸馏及馏出物保温装置,收集 350℃前馏出物,以四氢萘作为内标物,通过气相色谱法分析出馏出物中的萘含量,进而计算出煤焦油中萘含量.试验结果表明:该方法具有良好的准确度和精密度,并且能够防止煤焦油堵塞色谱毛细管柱.
Study on analysis of naphthalene content in coal tar with distillation chromatography
Naphthalene content in coal tar is an important indicator of tar ex-factory test.Aiming at the problem that chromatographic analysis of naphthalene in coal tar would block the chromatographic column,the study was made to use distillation-chromatography to analyze the naphthalene content in coal tar.The coal tar was distilled by the insulation device,and the distillate below 350℃was collected.Tetrahydronaphthalene was used as the internal standard,the naphthalene content in the distillate was analyzed by gas chromatography,and then the naphthalene content in coal tar was calculated.The experimental results showed that this method had good accuracy and precision and could prevent coal tar from blocking the chromatographic capillary column.

coal tardistillation-gas chromatographynaphthaleneinsulation device

秦云、余雷、张涛、喻婷

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武汉平煤武钢联合焦化有限责任公司,湖北 武汉 430080

煤焦油 蒸馏-气相色谱法 保温装置

2024

煤化工
赛鼎工程有限公司(原中国化学工业第二设计院),全国煤化工信息站,全国煤化工设计技术中心

煤化工

CSTPCD
影响因子:0.629
ISSN:1005-9598
年,卷(期):2024.52(1)
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