首页|GSP干煤粉气化炉气化灰渣特性研究及其掺烧利用分析

GSP干煤粉气化炉气化灰渣特性研究及其掺烧利用分析

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为实现煤气化灰渣资源化、减量化、无害化利用,对某GSP干煤粉气化炉气化细渣和气化粗渣进行分析,研究气化灰渣的化学组成、粒径分布、显微结构、灰熔融特性和燃烧特性,并对其综合利用方向提出建议.结果表明:气化粗渣和气化细渣的烧失量分别为 1.14%、35.15%,发热量分别为 0.38 MJ/kg、10.83 MJ/kg;气化细渣和粗渣的主要化学组成是SiO2、Al2O3、Fe2O3、CaO,粗渣中SiO2、Fe2O3、Al2O3 质量分数总和为 79.40%,粗渣可做建材、建工类原料使用;气化细渣的比表面积为 203.01 m2/g,平均孔径为 5.61 nm,具备制备吸附剂和活性炭的潜质;气化细渣的燃烧失重率为 34.74%,接近其烧失量,说明气化细渣具有一定燃烧反应活性;氧气浓度的增加可以明显改善气化细渣的燃烧特性.气化细渣掺烧再利用经济性分析结果表明:气化细渣掺烧不仅能够替代部分燃料煤,节约燃料成本,还可实现气化细渣资源化利用.
Research on characteristics of gasification slag in GSP dry pulverized coal gasifier and analysis of its co-combustion utilization
In order to achieve the resource utilizatio n,reduction and harmless utilization of coal gasification slag,an analysis was conducted on the gasification fine and coarse slag of one GSP gasifier.The chemical composition,particle size distribution,microstructure,ash melting characteristics and combustion characteristics of the gasification slag were studied,and suggestions were put forward for its comprehensive utilization direction.The results showed that the loss on ignition of gasification coarse and fine slag was 1.14%and 35.15%,respectively,and the heat generation was 0.38 MJ/kg and 10.83 MJ/kg,respectively.The main chemical components of gasification fine and coarse slag were SiO2,Al2O3,Fe2O3 and CaO.The total mass fraction of SiO2,Fe2O3 and Al2O3 in coarse slag was 79.40%.Coarse slag could be used as raw material for building materials and construction.The specific surface area of fine slag was 203.01 m2/g,with an average pore size of 5.61 nm,which had the potential of making adsorbent and activated carbon.The combustion weight loss rate of gasification fine slag was 34.74%,which was close to its combustion loss,indicating that fine slag had certain combustion reaction activity.The increase in oxygen concentration could significantly improve the combustion characteristics of gasification fine slag.The economic analysis results of gasification fine slag co-combustion utilization showed that gasification fine slag co-combustion could not only replace some fuel coal and save fuel cost,but also achieve the resource utilization of gasification fine slag.

GSP dry pulverized coal gasificationgasification fine slaggasification coarse slagcombustion characteristicsco-combustion utilization

杜钢、范佳明、杨会军

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国家能源集团宁夏煤业有限责任公司,宁夏 银川 750411

GSP干煤粉气化技术 气化细渣 气化粗渣 燃烧特性 掺烧利用

2024

煤化工
赛鼎工程有限公司(原中国化学工业第二设计院),全国煤化工信息站,全国煤化工设计技术中心

煤化工

CSTPCD
影响因子:0.629
ISSN:1005-9598
年,卷(期):2024.52(2)
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