首页|表面活性剂对煤层瓦斯解吸性能的影响

表面活性剂对煤层瓦斯解吸性能的影响

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为了探究表面活性剂对煤层瓦斯解吸性能的影响,以鄂尔多斯盆地某煤矿区的软煤样和硬煤样为研究对象,测定了不同类型表面活性剂溶液的表面张力和其在煤样表面的接触角,通过瓦斯解吸实验考察了表面活性剂对不同煤样瓦斯解吸量的影响,并对表面活性剂降低瓦斯解吸量的作用机理进行了分析.结果表明:当表面活性剂的质量分数为 0.3%时,复配型表面活性剂FH-18 对水溶液表面张力的降低效果最好,可使表面张力降低至23.5 mN/m;阴离子型表面活性剂SDBS在煤样表面的接触角最小,其在软煤样和硬煤样表面的接触角分别为 12.6°和 16.5°,煤样表面的润湿性能明显改善.不同类型的表面活性剂均能使煤样中的瓦斯解吸量降低,其中FH-18 抑制瓦斯解吸的效果最好,与空白干燥煤样相比,经过FH-18 处理后的软煤样和硬煤样的瓦斯解吸量分别可以降低70.48%和 67.55%.
Effect of surfactant on desorption performance of coal seam gas
In order to investigate the effect of surfactant on the desorption performance of coal seam gas,soft and hard coal samples from a coal mine area in the Ordos Basin were taken as the research objects.The surface tension of different types of surfactant aqueous solutions and their contact angles on the surface of coal samples were measured.The effect of surfactants on gas desorption in different coal samples was investigated through gas desorption experiments,and the mechanism of surfactant reducing the gas desorption was analyzed.The results showed that when the mass fraction of surfactant was 0.3%,the composite surfactant FH-18 had the best effect on reducing the surface tension of aqueous solution,which could reduce the surface tension to 23.5 mN/m.The anionic surfactant SDBS had the smallest contact angle on the surface of coal samples,with a contact angle of 12.6°and 16.5°on the surfaces of soft and hard coal samples,respectively.The wettability of the coal sample surface was significantly improved.Different types of surfactants could reduce the amount of gas desorption in coal samples,among which FH-18 had the best inhibitory effect on gas desorption.Compared with blank dry coal samples,the gas desorption of soft and hard coal samples treated with FH-18 could be reduced by 70.48%and 67.55%,respectively.

coal seamsurfactantgasdesorption performancedesorption amountwettability

胡良兆

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中煤科工集团重庆研究院有限公司,重庆 400037

煤层 表面活性剂 瓦斯 解吸性能 解吸量 润湿性能

重庆市自然科学基金面上资助项目

cstc2020jcyjmsxmX8259

2024

煤化工
赛鼎工程有限公司(原中国化学工业第二设计院),全国煤化工信息站,全国煤化工设计技术中心

煤化工

CSTPCD
影响因子:0.629
ISSN:1005-9598
年,卷(期):2024.52(3)