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炼化装置换热器腐蚀原因分析及控制措施研究

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为了降低炼化厂换热器的腐蚀速率,延长其使用寿命,采用挂片失重法对目标炼化装置换热器在不同因素条件下的腐蚀速率进行了评价,并在此基础之上,针对性地开展了腐蚀控制措施研究,评价了新型抗高温缓蚀剂HTS-2 对腐蚀防护效果的影响.实验结果表明:实验温度、流体流速、腐蚀介质pH值以及矿化度等因素均是引起炼化装置换热器腐蚀的主要原因,实验温度越高、流体流速越大、腐蚀介质矿化度越高,腐蚀速率越大;而腐蚀介质的pH值越高,腐蚀速率越小;当实验温度为 60℃、流体流速为 0.30 m/s、腐蚀介质pH值为 6、腐蚀介质矿化度为 2 860 mg/L时,腐蚀速率达到 1.559 mm/a,腐蚀较为严重;抗高温缓蚀剂HTS-2 质量分数为 2%时,可使 100℃下的腐蚀速率降低至 0.064 mm/a,能够满足炼化装置换热器等部件在高温条件下的腐蚀防护需求.
Cause analysis and control measure study on heat exchanger corrosion in refining plant
In order to reduce the corrosion rate of heat exchangers in refineries and extend their service life,the coupon weight loss method was used to evaluate the corrosion rate of heat exchangers in target refining plant under different factors.Based on this,the pertinent corrosion control measures were studied,and the influence of new high-temperature resistant corrosion inhibitor HTS-2 on the corrosion protection effect was evaluated.The experimental results showed that the main causes of corrosion in the heat exchanger of the refining plant were experimental temperature,fluid flow rate,pH value and mineralization degree of the corrosive medium.The higher the experimental temperature,the greater the fluid flow rate,and the higher the mineralization degree of the corrosive medium,the higher the corrosion rate.The higher the pH value of the corrosive medium,the lower the corrosion rate.When the experimental temperature was 60℃,the fluid flow rate was 0.30 m/s,the pH value of the corrosive medium was 6,and the mineralization degree of the corrosive medium was 2 860 mg/L,the corrosion rate could reach 1.559 mm/a,indicating severe corrosion.When the mass fraction of the high-temperature resistant corrosion inhibitor HTS-2 was 2%,it could reduce the corrosion rate to 0.064 mm/a at 100℃,meeting the corrosion protection requirements of the heat exchanger and other components of the refinery under high temperature condition.

refining plantheat exchangercorrosion reasoncorrosion rateinfluencing factorcorrosion inhibitor

张迎春、张艺莹、王珅

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四川石化责任有限公司,四川 成都 611930

炼化装置 换热器 腐蚀原因 腐蚀速率 影响因素 缓蚀剂

2024

煤化工
赛鼎工程有限公司(原中国化学工业第二设计院),全国煤化工信息站,全国煤化工设计技术中心

煤化工

CSTPCD
影响因子:0.629
ISSN:1005-9598
年,卷(期):2024.52(4)
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