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兖矿高硫油页岩热解特性的试验研究

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为获得兖矿高硫油页岩最优热解条件,通过管式炉热解试验装置,研究了热解终温、升温速率、反应时间和反应氛围对高硫油页岩热解特性的影响.结果表明:热解终温是决定页岩油产率和热解气组分的主要因素,最优反应条件为热解终温 540℃,升温速率 5℃/min,反应时间 30 mim~60 min;H2 氛围下页岩油产率有明显提高,H2 和CO2 热解氛围能促进油页岩的有机质分解,得到的页岩半焦中硫含量明显低于N2 气氛.
Experimental study on pyrolysis characteristics of high-sulfur oil shale in Yankuang Energy
To obtain optimal pyrolys is conditions for high-sulfur oil shale,the impacts of final pyrolysis temperature,heating rate,reaction time and reaction atmosphere on the pyrolysis characteristics of high-sulfur oil shale were studied through a tubular furnace pyrolysis test device.The results showed that the final pyrolysis temperature was the main factor determining the yield of shale oil and the composition of pyrolysis gas.The optimal reaction conditions were final pyrolysis temperature of 540℃,heating rate of 5℃/min,and reaction time of 30 min-60 min.The yield of shale oil had significantly increased under the H2 atmosphere,and the pyrolysis atmosphere of H2 and CO2 could promote the decomposition of organic matter in oil shale,resulting in a much lower sulfur content in shale semi-coke compared to that under the N2 atmosphere.

high-sulfur oil shalepyrolysis characteristicsfinal pyrolysis temperatureheating ratereaction timereaction atmospheresulfur element distribution

马刚、马俊鹏、宋金建、王士兵、宋凤霞、孔凡新、周忠鲲、吴鹏

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兖矿能源集团股份有限公司,山东 邹城 273500

山东华聚能源股份有限公司,山东 邹城 273500

北京国电富通科技发展有限责任公司,北京 100070

高硫油页岩 热解特性 热解终温 升温速率 反应时间 反应氛围 硫元素分布

2024

煤化工
赛鼎工程有限公司(原中国化学工业第二设计院),全国煤化工信息站,全国煤化工设计技术中心

煤化工

CSTPCD
影响因子:0.629
ISSN:1005-9598
年,卷(期):2024.52(5)