首页|新型改性煤气化废渣的制备及其吸附含铬废水中Cr6+的研究

新型改性煤气化废渣的制备及其吸附含铬废水中Cr6+的研究

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为进一步提高煤气化废渣对含铬废水中Cr6+的吸附能力,以某热电厂的煤气化废渣为原料,使用质量分数为 16%的硝酸溶液作为主剂,加入增溶剂ZR-1,在超声波辅助条件下对其进行了化学改性,制备出了一种新型改性煤气化废渣MH-GWY,并考察了煤气化废渣改性前后的吸附效果,评价了吸附剂投加量、废水pH值、吸附时间和吸附温度对Cr6+去除率的影响.结果表明:在相同的实验条件下,新型改性煤气化废渣MH-GWY对模拟含铬废水中Cr6+的吸附效果明显优于原煤气化废渣GWY;当废水含Cr6+质量浓度为 100 mg/L时,100 mL废水中加入 0.3 g吸附剂MH-GWY,控制废水pH值为 5,吸附时间为 160 min,吸附温度为 25℃,Cr6+去除率可以达到 96.75%.
Study on preparation of new modified coal gasification waste residue and its adsorption of Cr6+in chromium-containing wastewater
In order to further improve the adsorption capacity of coal gasification waste residue for Cr6+in chromium-containing wastewater,a new type of modified coal gasification waste residue MH-GWY was prepared by using coal gasification waste residue from a thermal power plant as raw material,16%nitric acid solution as the main agent and adding a solubilizer ZR-1,which had chemical modification under ultrasound assisted conditions.The adsorption effect of coal gasification waste residue before and after modification was investigated,and the impacts of adsorbent dosage,wastewater pH value,adsorption time and adsorption temperature on the removal rate of Cr6+were evaluated.The results showed that under the same experimental conditions,the adsorption effect of the new modified coal gasification waste residue MH-GWY on Cr6+in simulated chromium-containing wastewater was clearly better than that of the original coal gasification waste residue GWY.When the concentration of Cr6+in the wastewater was 100 mg/L,0.3 g of adsorbent MH-GWY was added to 100 mL of wastewater,the pH value of the wastewater was controlled at 5,the adsorption time was 160 min,and the adsorption temperature was 25℃,the removal rate of Cr6+could reach 96.75%.

coal gasification waste residueultrasonic assisted chemical modificationwastewater containing Cr6+adsorptioninfluence factor

张蒙蒙、段兰苹、吴蕊、李晓堂

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沧州医学高等专科学校,河北 沧州 061000

煤气化废渣 超声波辅助化学改性 含Cr6+废水 吸附 影响因素

沧州医学高等专科学校科研项目

19Z010

2024

煤化工
赛鼎工程有限公司(原中国化学工业第二设计院),全国煤化工信息站,全国煤化工设计技术中心

煤化工

CSTPCD
影响因子:0.629
ISSN:1005-9598
年,卷(期):2024.52(5)