能源环境保护2024,Vol.38Issue(1) :134-142.DOI:10.20078/j.eep.20240119

Mn/炭黑-泡沫镍电极电化学降解诺氟沙星

Electrochemical treatment of norfloxacin with Mn/carbon black-nickel foam electrodes

李阳 陈琳 黄心睿 文志潘 明银安 王营茹
能源环境保护2024,Vol.38Issue(1) :134-142.DOI:10.20078/j.eep.20240119

Mn/炭黑-泡沫镍电极电化学降解诺氟沙星

Electrochemical treatment of norfloxacin with Mn/carbon black-nickel foam electrodes

李阳 1陈琳 1黄心睿 1文志潘 2明银安 1王营茹1
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作者信息

  • 1. 武汉工程大学化学与环境工程学院,湖北武汉 430205
  • 2. 武汉纺织大学纺织新材料与先进加工技术国家重点实验室,湖北武汉 430200
  • 折叠

摘要

电化学法降解水中有机污染物具有低碳、高效等特点.本文采用共沉淀法制备Mn/炭黑-泡沫镍电极,通过场发射扫描电镜(FESEM)、X射线光电子能谱(XPS)对电极进行了表征,考察了外加电压、极板间距、电解质浓度和诺氟沙星初始浓度对其降解效果的影响.结果表明,Mn/炭黑-泡沫镍电极可促进·OH的产生,强化电芬顿效果.钛钌-Mn/炭黑-泡沫镍电极在外加电压6 V,极板间距15 mm,电解质浓度20 mmol/L,诺氟沙星初始浓度10 mg/L条件下,诺氟沙星去除率可达83.9%,TOC去除率69.2%,能耗为9.6 kW·h/m3.对比钛钌-泡沫镍电极,在相同条件下,Mn/炭黑-泡沫镍电极的诺氟沙星去除率提高了15.8%,能耗降低了0.6 kW.h/m3,并且电流效率提高,反应速率明显加快,表明该电极对抗生素类污染物降解具有较好的催化作用.

Abstract

Electrochemical degradation is a promising method for removing organic pollutants from water due to its low carbon footprint and high efficiency.In this study,we prepared Mn/carbon black-nickel foam electrodes using a co-precipitation method and characterized them using FESEM and X-ray photoelectron spectroscopy.We investigated the effects of applied voltage,plate spacing,elec-trolyte concentration,and initial norfloxacin concentration on the degradation of organic pollutants.The results indicated that Mn/carbon black-nickel foam electrodes exhibited excellent performance in pro-moting the generation of hydroxyl radicals(·OH)and enhancing the electro-Fenton effect.At optimal conditions,including an applied voltage of 6 V,plate spacing of 15 mm,electrolyte concentration of 20 mmol/L,and initial norfloxacin concentration of 10 mg/L,the norfloxacin removal percentage reached 83.9%.Additionally,the total organic carbon(TOC)removal percentage was 69.2%,and the energy consumption was 9.6 kW·h/m3.Furthermore,when compared to titanium ruthenium-nickel foam electrodes under the same conditions,the Mn/carbon black-nickel foam electrode exhibited a 15.8%increase in norfloxacin removal rate,a reduction of 0.6 kW·h/m3 in energy consumption,improved current efficiency,and significantly accelerated reaction rates.Overall,this study demonstrates the ex-cellent catalytic effect of the Mn/carbon black-nickel foam electrode on the degradation of antibiotic pollutants.

关键词

电化学降解/有机污染物/Mn/炭黑-泡沫镍电极/诺氟沙星

Key words

Electrochemical degradation/Organic pollutants/Mn/carbon black-nickel foam electrodes/Norfloxacin

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基金项目

国家自然科学基金资助项目(52170170)

武汉工程大学第十四届研究生教育创新基金资助项目(CX2022434)

出版年

2024
能源环境保护
煤炭科学研究总院杭州环境保护研究所

能源环境保护

影响因子:0.472
ISSN:1006-8759
参考文献量34
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