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焦油模型物与木屑共热解产物分布规律研究

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利用甲苯和乙酸为焦油模型物,以杉木屑为原料,在一级固定床反应系统中进行共热解实验,以实现木屑热解最大化脱除焦油产气,并探讨不同温度下共热解产物分布规律及产物之间的协同作用.结果表明,与木屑单独热解相比,木屑与甲苯、乙酸共热解产生的协同作用呈现出优越的焦油脱除效果.尤其,木屑与甲苯共热解可有效地将焦油产率减少81.47%,从焦油组分来看,含氧类化合物在共热解过程中不能有效脱除,而芳烃类化合物在热解过程中易通过高温共热解脱除,乙酸与木屑共热解的协同作用较甲苯强度稍弱.共热解产物产率变化受温度影响显著,其变化规律与纯木屑单独热解一致,热解温度升高对半焦、焦油的抑制效果增强,为焦油脱除及高效转化提供了理论基础.
Study on the distribution law of co-pyrolysis products of tar models and sawdust
In this study,toluene and acetic acid were investigated as model biomass tars,and sawdust was used as the feedstock.Co-pyrolysis experiments were conducted in a first-order fixed-bed reaction system to maximize the tar removal from sawdust.The distribution of co-pyrolysis products at different temperatures and the synergistic effects among the products were discussed.The results showed that compared to the pyrolysis of sawdust alone,the co-pyrolysis of sawdust with toluene and acetic acid ex-hibited a superior tar removal effect.Specifically,the co-pyrolysis of sawdust and toluene effectively reduced the tar yield by 81.47%.From the perspective of tar components,oxygen-containing com-pounds could not be effectively removed during the co-pyrolysis process,while aromatic hydrocarbons were easy to be removed by high-temperature co-pyrolysis.The synergistic effect of co-pyrolysis of acetic acid and sawdust was slightly weaker than that of toluene.The yield change of co-pyrolysis prod-ucts affected by temperature was consistent with that of sawdust pyrolysis alone.Furthermore,the inhib-itory effect of pyrolysis temperature on coke and tar was enhanced,providing a reference for tar removal and efficient conversion.

Tar modelSawdustCo-pyrolysisPyrolysis temperatureProduct distribution

李学琴、刘鹏、王玲玲、呼和涛力、王志伟、雷廷宙

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常州大学城乡矿山研究院常州市生物质绿色安全高值利用技术重点实验室,江苏常州 213164

华东理工大学资源与环境工程学院能源化工系,上海 200237

河南工业大学环境工程学院,河南郑州 450001

河南工业大学碳中和研究院,河南郑州 450001

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焦油模型物 木屑 共热解 热解温度 产物分布

国家重点研发计划江苏省碳达峰碳中和科技创新专项

2022YFB4201901BE2022426

2024

能源环境保护
煤炭科学研究总院杭州环境保护研究所

能源环境保护

影响因子:0.472
ISSN:1006-8759
年,卷(期):2024.38(2)
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