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铜冶炼车间回用水分盐中试试验研究

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为实现废水的近零排放和资源化处理,采用"生物制剂与双碱法协同脱钙+反渗透装置浓缩+纳滤装置分盐+电渗析装置浓缩+蒸发结晶装置出盐"工艺处理某铜冶炼车间回用水.结果表明,SO42-截留率>99%,Na2SO4浓水溶解性总固体(TDS)质量浓度达179 g/L,NaCl浓水TDS质量浓度达150 g/L,浓缩液蒸发结晶后得到Na2SO4与NaCl产品盐.Na2SO4达到GB/T 6009-2014《工业无水硫酸钠》二类合格品要求,NaCl满足GB/T 5462-2015《工业盐质量标准》中一级标准.解决了回用水浓水浓度低、Na2SO4产品为杂盐等问题,为有色行业经济高效地处理高含盐废水奠定了工程化基础.
Pilot test and research of desalination in recycle water in copper smelting workshop
In order to realize Near Zero Emission and resource utilization in wastewater treatment,the reuse water from a copper smelting workshop was treated using a process involving biological agents,double alkali decalcification,reverse osmosis concentration,nanofiltration salt separation,electrodialysis concentration,and evaporation crystallization salt removal.The experimental result shows that the retention rate of SO42-reaches>99%,the total soluble solids(TDS)of Na2SO4 in concentrated water reaches 179 g/L,and the TDS of NaCl in concentrated water can reach 150 g/L.After concentration and separation,Na2SO4 and NaCl salt product are precipitated,and Na2SO4 meets the requirements of Class Ⅱqualified product defined in GB/T 6009-2014 Industrial Anhydrous Sodium Sulfate,and NaCl meets the Class Ⅰ standard defined in GB/T 5462-2015 Industrial Salt Quality Standard.This process solves the problem of low concentration in recycled concentrated water and removes the impurities in Na2SO4 products,providing bases for the cost-effective engineering treatment of high salty wastewater in the non-ferrous industry.

copper smelterreuse watersalt separation with NF

刘永丰、蒋国民、朱赞强、颜鲜林、桂俊峰、刘锐利

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赛恩斯环保股份有限公司,长沙 410000

有色重金属污染治理装备湖南省工程实验室,长沙 410000

有色行业污染治理与装备工程技术研究中心,长沙 410000

铜冶炼厂 回用水 纳滤分盐

湖南省环保科研课题

HBKT-2022013

2024

膜科学与技术
中国蓝星(集团)股份有限公司

膜科学与技术

CSTPCD北大核心
影响因子:0.634
ISSN:1007-8924
年,卷(期):2024.44(2)
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