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电催化膜技术工艺处理含酚废水的研究进展

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苯酚、双酚A、4-硝基苯酚等酚类化合物是石化和化工废水中常见的高毒性难降解有机污染物.吸附、化学氧化、生化降解等传统技术方法很难将它们高效完全去除."双碳"背景下,研发高效的难降解污染物治理新方法有助于推进环境污染治理和实现绿色可持续发展目标.电催化膜技术是将膜过滤与电化学高级氧化相结合的新技术工艺,具有高效、无二次污染等诸多优点,逐渐成为本领域的一个重要发展方向.本文首先简要概述含酚废水的来源、危害及传统处理方法,然后从电催化膜作用机理、膜电极材料、电催化膜工艺处理酚类污染物的主要影响因素、电催化膜与相关技术结合处理含酚废水等方面系统介绍和总结近年来的研究进展,分析了电催化膜工艺的优势和存在的问题,并对其发展趋势和应用前景进行了展望,以期为后续研究和应用技术开发提供参考、启发和借鉴.
Advances in treatment of wastewater containing phenolic compounds via electrocatalytic membrane process
Phenolic compounds such as phenol,bisphenol A,and 4-nitrophenol are common high toxic and difficult to degrade organic pollutants in the wastewater produced from petrochemical and chemical industries.Traditional techniques such as adsorption,chemical oxidation,and biochemical degradation etc.are difficult to remove them efficiently and completely.Under the background of"dual carbon",the research and development of new methods for treating those pollutants are benefit for environmental protection and achieving the goal of green and sustainable development.Electrocatalytic membrane technology is a new technology that combines membrane filtration with electrochemical advanced oxidation.It has advantages such as high efficiency and no secondary pollution etc.,and has gradually become an important development direction in the field of treating organic pollutants.In this article,we firstly give a brief overview of the sources,hazards,and traditional treatment methods of phenolic wastewater.Then,the recent research progress of the mechanisms of removal of phenolic pollutants via electrocatalytic membranes,the design and preparation of membrane electrode materials,the main influencing factors of electrocatalytic membrane process for treating phenolic pollutants,and the combination of electrocatalytic membranes and related technologies for treating phenolic wastewater are introduced systematically.The development status,advantages,existing problems,and challenges of this technology are also analyzed and summarized.At last,the prospect of electrocatalytic membranes process applied to treat of phenolic wastewater is proposed.

phenolic organic compoundsphenolic wastewaterelectrocatalytic membrane technologymembrane electrode material

王建宇、陈榕汶、方传杰、朱利平

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浙江大学绍兴研究院大健康材料分中心,绍兴 312000

浙江大学膜与水处理技术教育部工程研究中心,杭州 310030

浙江大学高分子科学与工程学系,杭州 310030

酚类有机化合物 含酚废水 电催化膜技术 膜电极材料

浙江省"尖兵领雁"研发攻关计划项目

2024C03132

2024

膜科学与技术
中国蓝星(集团)股份有限公司

膜科学与技术

CSTPCD北大核心
影响因子:0.634
ISSN:1007-8924
年,卷(期):2024.44(4)
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