膜科学与技术2024,Vol.44Issue(5) :47-56.DOI:10.16159/j.cnki.issn1007-8924.2024.05.006

单宁酸辅助剥离的MoS2/BNC复合膜渗透能转换性能研究

Composite membrane consisting of molybdenum disulfide/bacterial cellulose nanofibres for osmotic energy conversion using tannic acid-assisted etching

王旭颖 杨靖 王钊毅 张庆萧 范议议 孟秀霞
膜科学与技术2024,Vol.44Issue(5) :47-56.DOI:10.16159/j.cnki.issn1007-8924.2024.05.006

单宁酸辅助剥离的MoS2/BNC复合膜渗透能转换性能研究

Composite membrane consisting of molybdenum disulfide/bacterial cellulose nanofibres for osmotic energy conversion using tannic acid-assisted etching

王旭颖 1杨靖 1王钊毅 1张庆萧 1范议议 1孟秀霞1
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作者信息

  • 1. 山东理工大学化学化工学院,淄博 255049
  • 折叠

摘要

利用一步水热法制备了二硫化钼/细菌纤维素纳米纤维(MoS2/BNC)复合材料,通过单宁酸(TA)辅助剥离成功制备了大横向尺寸的TA-MoS2/BNC纳米片;采用真空辅助过滤的方法制备了聚醚砜(PES)支撑的TA-MoS2/BNC复合膜,其抗拉强度、破坏应力、屈服应力随着TA含量的增加而增加,当TA质量浓度为200 mg/mL时,其值分别为10.04、2.38和7.78 MPa,显示了较好的组装性能.有效测试面积为7.07 mm2(约为传统膜测试面积3.4× 104 μm2的207倍)的TA-MoS2/BNC复合膜表现出了较高的Na+选择性.盐差浓度为50倍时,输出功率密度为8.79 W/m2,盐差浓度为100倍时,输出功率密度达到最高14.18 W/m2,远高于文献报道.这些将为渗透能在较大面积下的高效转换提供有力支撑.

Abstract

Molybdenum disulfide/bacterial cellulose nanofibres(MoS2/BNC)composites were prepared by one-step hydrothermal method.A large-size TA-MoS2/BNC nanosheets obtained by tannic acid(TA)-assisted exfoliation.The polyethersulfone(PES)supported composite membranes were successfully prepared by vacuum-assisted filtration.The tensile strength,failure stress,and yield strength of the resultant TA-MoS2/BNC composite membrane is up to 10.04 MPa,2.38 MPa and 7.78 MPa,respectively,showing high-performance assembling.The highly Na+ion-selective TA-MoS2/BNC composite membranes with the thickness of 870 nm produced an output power density of 8.79 W/m2 at an effective area of 7.07 mm2,which is about 207 times larger than that of the conventional testing area of 3.4×104 pm2,and captured an output power density of 14.18 W/m2 under a 100-fold salinity gradient,exceeding the reported membrane.These provide a strong guarantee of efficient conversion of osmotic energy for MoS2-based membrane.

关键词

渗透能转换/二硫化钼/复合膜/单宁酸/细菌纤维素

Key words

osmotic energy conversion/molybdenum disulfide/composite membrane/tannic acid/bacterial nanocellulose

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基金项目

国家自然科学基金项目(21978157)

山东省自然科学基金项目(ZR2022QB147)

山东省自然科学基金项目(ZR2023MB093)

出版年

2024
膜科学与技术
中国蓝星(集团)股份有限公司

膜科学与技术

CSTPCDCSCD北大核心
影响因子:0.634
ISSN:1007-8924
参考文献量55
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