首页|单宁酸辅助剥离的MoS2/BNC复合膜渗透能转换性能研究

单宁酸辅助剥离的MoS2/BNC复合膜渗透能转换性能研究

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利用一步水热法制备了二硫化钼/细菌纤维素纳米纤维(MoS2/BNC)复合材料,通过单宁酸(TA)辅助剥离成功制备了大横向尺寸的TA-MoS2/BNC纳米片;采用真空辅助过滤的方法制备了聚醚砜(PES)支撑的TA-MoS2/BNC复合膜,其抗拉强度、破坏应力、屈服应力随着TA含量的增加而增加,当TA质量浓度为200 mg/mL时,其值分别为10.04、2.38和7.78 MPa,显示了较好的组装性能.有效测试面积为7.07 mm2(约为传统膜测试面积3.4× 104 μm2的207倍)的TA-MoS2/BNC复合膜表现出了较高的Na+选择性.盐差浓度为50倍时,输出功率密度为8.79 W/m2,盐差浓度为100倍时,输出功率密度达到最高14.18 W/m2,远高于文献报道.这些将为渗透能在较大面积下的高效转换提供有力支撑.
Composite membrane consisting of molybdenum disulfide/bacterial cellulose nanofibres for osmotic energy conversion using tannic acid-assisted etching
Molybdenum disulfide/bacterial cellulose nanofibres(MoS2/BNC)composites were prepared by one-step hydrothermal method.A large-size TA-MoS2/BNC nanosheets obtained by tannic acid(TA)-assisted exfoliation.The polyethersulfone(PES)supported composite membranes were successfully prepared by vacuum-assisted filtration.The tensile strength,failure stress,and yield strength of the resultant TA-MoS2/BNC composite membrane is up to 10.04 MPa,2.38 MPa and 7.78 MPa,respectively,showing high-performance assembling.The highly Na+ion-selective TA-MoS2/BNC composite membranes with the thickness of 870 nm produced an output power density of 8.79 W/m2 at an effective area of 7.07 mm2,which is about 207 times larger than that of the conventional testing area of 3.4×104 pm2,and captured an output power density of 14.18 W/m2 under a 100-fold salinity gradient,exceeding the reported membrane.These provide a strong guarantee of efficient conversion of osmotic energy for MoS2-based membrane.

osmotic energy conversionmolybdenum disulfidecomposite membranetannic acidbacterial nanocellulose

王旭颖、杨靖、王钊毅、张庆萧、范议议、孟秀霞

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山东理工大学化学化工学院,淄博 255049

渗透能转换 二硫化钼 复合膜 单宁酸 细菌纤维素

国家自然科学基金项目山东省自然科学基金项目山东省自然科学基金项目

21978157ZR2022QB147ZR2023MB093

2024

膜科学与技术
中国蓝星(集团)股份有限公司

膜科学与技术

CSTPCD北大核心
影响因子:0.634
ISSN:1007-8924
年,卷(期):2024.44(5)