工矿自动化2024,Vol.50Issue(9) :161-166.DOI:10.13272/j.issn.1671-251x.2024050064

机械冲击条件下锂离子蓄电池安全性分析

Safety analysis of lithium-ion batteries under mechanical shock conditions

倪春明
工矿自动化2024,Vol.50Issue(9) :161-166.DOI:10.13272/j.issn.1671-251x.2024050064

机械冲击条件下锂离子蓄电池安全性分析

Safety analysis of lithium-ion batteries under mechanical shock conditions

倪春明1
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作者信息

  • 1. 上海煤科检测技术有限公司,上海 201400
  • 折叠

摘要

煤矿井下环境恶劣且空间狭小,锂离子蓄电池容易遭受外部的物理冲击或损害,引发安全事故.以100 A·h矿用锰酸锂离子蓄电池作为研究对象,对该电池进行针刺、高温、潮湿试验,分析电池的安全性能.通过针刺试验模拟煤矿井下环境中潜在的机械冲击,用尖锐物体刺入电池,观察电池在极端条件下的反应.使用炉箱和湿度控制环境箱模拟煤矿井下的高温和潮湿环境,对针刺后的电池实施试验,评估电池在煤矿井下极端环境中的安全性和可靠性.试验结果表明:① 电池被钨针刺穿后,表面出现一定变形和破裂,但未出现电解质泄漏的情况,同时电池并未出现冒烟、起火、爆炸等危险情况,内部也没有气体产生.被钨针刺穿后,电池温度显著上升,但能控制在安全范围内且没有引发燃烧或爆炸,说明该电池在煤矿井下应用中具有一定的热稳定性.② 被刺穿电池在炉箱加热后显著膨胀,并伴随有气体泄漏的现象,但尚未引发爆炸或燃烧,说明电池在特定条件下具有一定的热稳定性.③ 在潮湿环境下,被刺穿电池产生气体,增加了内部压力,在刺穿和潮湿的双重影响下,使得电池温度增加,但因为潮湿环境中的水分起到一定的冷却作用,与高温环境下相比,电池温度上升趋势较为缓慢,且仍未引发爆炸或燃烧,说明电池在潮湿环境下仍具有热稳定性,不会出现热失控现象.

Abstract

The harsh and confined environment of underground coal mines makes lithium-ion batteries vulnerable to external physical shocks or damage,potentially leading to safety incidents.This study investigated a 100 A·h lithium manganese oxide ion battery designed for mining applications,employing puncture,high-temperature,and humidity tests to evaluate its safety performance.The puncture test simulated mechanical shocks typical in coal mine environments by penetrating the battery with a sharp object and observing its response under extreme conditions.A furnace and humidity-controlled environment chamber were also utilized to replicate the high-temperature and humid conditions encountered in coal mines,assessing the battery's safety and reliability post-puncture.The results revealed the following:① After puncture by a tungsten needle,the battery exhibited surface deformation and cracking,but no electrolyte leakage,smoke,fire,or explosion occurred,with no gas generation inside.Although the temperature of the punctured battery rose significantly,it remained within a safe range without igniting or exploding,indicating a certain level of thermal stability suitable for coal mine applications.② The punctured battery expanded notably when heated in the furnace,accompanied by gas leakage;however,no explosion or combustion took place,suggesting thermal stability under specific conditions.③ In a humid environment,the punctured battery produced gas,leading to increased internal pressure.The combination of puncture and humidity raised the battery's temperature,but the moisture acted as a cooling agent,resulting in a slower temperature increase compared to high-temperature conditions,without triggering explosion or combustion.This indicated that the battery maintained thermal stability in humid environments and did not exhibit thermal runaway.

关键词

矿用锰酸锂离子蓄电池/电池安全性试验/机械冲击/针刺试验/高温试验/潮湿试验

Key words

lithium manganese oxide ion battery for mining/battery safety testing/mechanical shock/puncture testing/high-temperature testing/humidity testing

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基金项目

国家发展和改革委项目(0732118)

出版年

2024
工矿自动化
中煤科工集团常州研究院有限公司

工矿自动化

CSTPCDCSCD北大核心
影响因子:0.867
ISSN:1671-251X
参考文献量21
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