首页|基于巷道伸缩缝的环氧一聚氨酯止水材料试验研究

基于巷道伸缩缝的环氧一聚氨酯止水材料试验研究

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在地下矿山工程漏水情况中,因巷道伸缩缝漏水问题占其总漏水情况近90%,伸缩缝漏水是地下矿山工程的主要灾害,对地下建筑物带来严重的安全隐患.为了改善巷道伸缩缝的止水堵漏情况,通过将聚氨酯与环氧树脂聚合制备的止水材料,目前常用的方法是对水性聚氨酯进行改性,以增强聚氨酯材料的物理力学性能,使得材料在巷道伸缩缝止水应用更加广泛.使用环氧树脂对水性聚氨酯进行改性,采用理论和试验研究法将环氧值、环氧树脂含量和反应温度作为3个主要变量,分析其对聚氨酯材料性能的影响.结果表明,研究不同环氧值时采用环氧树脂E-4和环氧树脂E-51对水性聚氨酯进行改性,环氧树脂E-51改性的聚氨酯材料的抗压强度、黏度等性能要优于环氧树脂E-44.随着反应温度的增加聚氨酯材料的凝结速率逐渐加快,凝结时间逐渐减低.环氧树脂E-51能够提高聚氨酯材料的物理力学性能,当环氧树脂的含量为10%时聚氨酯材料的拉伸强度、抗压强度、黏结强度、止水水压和断裂伸长率分别为 0.70、0.77、1.12、0.50 MPa 和 95%.
Experimental study of epoxy-polyurethane waterproof materials based on roadway expansion joints
In the water leakage of underground mining engineering,the leakage of expansion joints in the roadway accounts for nearly 90%of the total water leakage,and the leakage of expansion joints is the main disaster of underground mining engineering,which brings serious safety hazards to underground buildings.In order to improve the water-stopping and leakage plugging of roadway expansion joints,the water-stopping materials prepared by polymerization of polyurethane and epoxy resin were modified to enhance the physical and mechanical properties of pol-yurethane materials,so that the materials can more widely used in water-stopping materials in roadway expansion joints.Epoxy resin was used to modify waterborne polyurethane,and the epoxy value,epoxy resin content and reaction temperature were taken as three main variables to analyze their effects on the properties of polyurethane materials.The results show that epoxy resin E-44 and epoxy resin E-51 were used to modify waterborne polyurethane when studying different epoxy values,and the compressive strength and viscosity of epoxy resin E-51 modified polyurethane material were better than those of epoxy resin E-44.With the increase of reaction temperature,the coagulation rate of polyure-thane materials gradually accelerates,and the coagulation time gradually decreases.Epoxy resin E-51 can improve the physical and mechanical properties of polyurethane materials,when the content of epoxy resin is 10%,the tensile strength,compressive strength,bonding strength,wa-terproof water pressure and elongation at break of polyurethane materials are 0.70,0.77,1.12,0.50 MPa and 95%,respectively.

waterborne polyurethaneepoxy resinexpansion jointreaction temperatureepoxy value

闫东、李肖飞、李士民、成帅、张雷、赵军

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信阳师范大学建筑与土木工程学院,河南信阳 464000

信阳师范大学河南省新型环保土木工程材料工程研究中心,河南信阳 464000

黄河水利委员会黄河水利科学研究院,河南郑州 450003

郑州大学土木工程学院,河南郑州 450003

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水性聚氨酯 环氧树脂 伸缩缝 反应温度 环氧值

2024

煤炭科技
江苏省徐州矿务集团有限公司 江苏省煤炭学会 中国矿业大学

煤炭科技

影响因子:0.17
ISSN:1008-3731
年,卷(期):2024.45(6)