首页|盐水层地质参数对CO2封存效果的评价

盐水层地质参数对CO2封存效果的评价

扫码查看
在二氧化碳捕集、利用与封存技术中,盐水层封存CO2 由于具有分布面积广和封存潜力大等多重优势,逐渐成为应对全球气候变暖、实现2050年世界净零目标、减少CO2 排放的有效方法。为提高盐水层中CO2 的封存效果,以国内外现有的相关地质封存项目数据为基础,采用Pet-rasim软件中的TOUGHREACT/ECO2N模块,选取CO2 溶解质量和气态CO2 饱和度为评价指标,通过数值模拟方法,从盐溶液体系和储层物性参数 2个方面,揭示地层盐水盐度、地层盐水组分、地层压力、地层温度和渗透率 5个地质参数对盐水层CO2 封存的影响机制,并定量评价CO2 封存效果。结果表明:①各地质参数主要通过改变CO2、地层盐水的密度和黏度、CO2 溶解度以及CO2-盐水-岩石的化学反应等,进而控制地层流体的溶解度、流动性和传质性;②CO2 的溶解度和地层盐水密度分别随盐度的增加而降低、增大,但前者受其影响程度更大,从而盐度对CO2 的溶解表现出抑制作用,因此低盐度的盐水层更有助于增加CO2 封存量及提高埋存安全性;③根据苏林分类法得到的 4种盐溶液组分中,CaCl2 水型对应的CO2 溶解质量略低于其他 3种水型,但整体上不同盐溶液组分对CO2 封存效果影响不大;④在CO2 溶解度和气液两相黏度比的共同作用下,CO2 溶解质量随压力和温度的增大而减少,气态CO2 饱和度变化相反;渗透率对气体流动性和运移距离起直接控制作用,因此地层压力和温度越低,渗透率越大的盐水层越有利于CO2 封存。
Evaluation of CO2 storage effected by geological parameters of brine layer
In the practice of carbon dioxide capture,utilization and storage,the storage of CO2 in salt water layer has gradually become an effective way to deal with global warming,achieving the goal of net zero in 2050 and reducing CO2 emissions due to its multiple advantages such as wide distribution area and large storage potential.TOUGHREACT/ECO2N module in the Petrasim software was adopted to improve the storage efficiency of CO2 in brine reservoirs.Based on the existing data of relevant geological storage projects in China and other countries,the numerical simulation method was used to evaluate the CO2 dissolution quality and gaseous CO2 saturation.The influence mechan-ism of five geological parameters of formation brine salinity,composition of formation brine,formation pressure,forma-tion temperature and permeability on CO2 sequestration was revealed,and the effect of CO2 sequestration was quantitat-ively evaluated.The results show that:①the geological parameters control the solubility,fluidity and mass transfer of formation fluids by changing the density and viscosity of CO2,formation brine,CO2 solubility and the chemical reaction of CO2-brine and rock.②The solubility of CO2 and the density of formation brine decrease and increase with the in-crease of salinity respectively,with the former being mostly affected.The salinity has an inhibitory effect on the dissolu-tion of CO2.Therefore,the brine layer with low salinity is more conducive to increasing the storage capacity of CO2 and improving the storage safety.③Among the four salt solution components obtained according to the Sulin classification method,the CO2 dissolution quality corresponding to CaCl2 water type is slightly lower than that of the other three water types.Overall,different salt solution components have little influence on the effect of CO2 storage.④Under the com-bined effect of CO2 solubility and gas-liquid two-phase viscosity ratio,the dissolved mass of CO2 decreases with the in-crease of pressure and temperature,while the gaseous CO2 saturation changes inversely.Permeability plays a direct role in controlling the gas mobility and migration distance.Therefore,with the lower formation pressure and temperature,the brine layer with higher permeability is more conducive to CO2 storage.

brine reservoirCO2 geologic storagegeological parameterdissolved mass of CO2gaseous CO2 satura-tion

张琳琳、赖枫鹏、董银涛、戴玉婷

展开 >

中国地质大学(北京)能源学院,北京 100083

中国石油长庆油田分公司物资供应处,陕西西安 710016

非常规天然气能源地质评价与开发工程北京市重点实验室,北京 100083

中海油研究总院有限责任公司,北京 100028

中国石油长庆油田分公司勘探开发研究院,陕西西安 710018

展开 >

盐水储层 CO2地质封存 地质参数 CO2溶解质量 气态CO2饱和度

2024

煤炭学报
中国煤炭学会

煤炭学报

CSTPCD北大核心
影响因子:3.013
ISSN:0253-9993
年,卷(期):2024.49(9)