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广州市地下咸水化学特征及海水入侵来源探究

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为探讨广州市海水入侵来源,通过分析研究广州地下水样品的离子特征和氢氧同位素特征、Cl-与Br-的相关关系和分布规律,并结合区域水文地质条件进行综合判断.结果显示ρ(Cl-)与ρ(Sr2+)具有强相关性,初步证明地下水咸化的原因是现代海水入侵.通过分析地下水样品与海水样品的ρ(Sr2+)/ρ(Cl-)与ρ(Sr2+)/ρ(Ca2+)比值,判断Sr2+还可来源于水岩间离子交换.通过聚类分析结果对不同点位的地下水进行分组,分组结果与离子特征分组结果相似,为地下水咸化原因的确定提供了更多证据.通过对比地下水和海水的氢氧同位素特征,发现δD和δ18O逐渐向海水过渡,指示了广州市地下水的补给来源和地下水的咸化趋势.δD和δ18O值与Cl-的质量浓度的正相关性,同样证明了广州市海水入侵区的地下水受到了海水的混染.
Research on hydrological characteristics of underground salty water and the sources of seawater intrusion in Guangzhou
To explore the sources of seawater intrusion in Guangzhou City,the ion characteristics and hydrogen and oxygen isotope characteristics,the correlation and distribution patterns between Cl-and Br-of groundwater samples in Guangzhou were analyzed and studied,and a comprehensive judgments was made based on regional hydrogeological conditions.The strong correlation between ρ(Cl-)and ρ(Sr2+)preliminarily proved that the cause of groundwater salinization was modern seawater intrusion.By comparing the ρ(Sr2+)/ρ(Cl-)and ρ(Sr2+)/ρ(Ca2+)of groundwater and seawater samples,it was determined that Sr2+could also originate from ion exchange between water and rock.Cluster analysis results were used to group groundwater at different locations,and the grouping results were similar to the ion characteristic grouping results,which provided more evidence for determining the cause of groundwater salinization.By comparing the hydrogen and oxygen isotope characteristics of groundwater and seawater,the gradual transition of δD and δ18O towards seawater indicated the source of groundwater recharge and the trend of groundwater salinization in Guangzhou.The positive correlation between the values of δD and δ18O and the mass concentration of Cl-also proved that the groundwater in the seawater intrusion area of Guangzhou was contaminated by seawater.

seawater intrusionstrontiumCl ion contentD~18O isotopes

王钊、闫淼

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广州市地质调查院,广东 广州 510440

海水入侵 锶元素 Cl离子含量 D~18O同位素

2024

南昌大学学报(工科版)
南昌大学

南昌大学学报(工科版)

影响因子:0.319
ISSN:1006-0456
年,卷(期):2024.46(4)