首页|木质素热解制备焦炭的试验研究

木质素热解制备焦炭的试验研究

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利用管式炉热解装置在不同温度下对工业废弃的木质素进行热解制备焦炭的试验研究,对热解焦炭的产率和各项指标进行了分析.结果表明:当热解温度从300℃升高至700 ℃时,焦炭产率从72.94%下降至39.79%;焦炭中固定碳含量不断升高,热值从29.19 MJ/kg逐步升高至31.62 MJ/kg;当热解温度从300℃升高至600℃时,焦炭的比表面积从0.47 m2/g迅速升至13.63 m2/g,碘吸附值由185.51 mg/g增大到320.64 mg/g,而随着热解温度继续升至700℃时,焦炭的比表面积和碘吸附值迅速降低.因此,热解温度有利于焦炭品质和吸附性能的提高,但过高的热解温度会对焦炭的吸附性能起到一定的抑制作用.
Experimental study on char produced from lignin pyrolysis
The lignin pyrolysis was performed at different pyrolysis temperatures on a lab-scale tube furnace pyrolysis reactor,it provided comprehensive information for yield and properties of pyrolysis char.The results are as follows:with increasing in pyrolysis temperature from 300 ℃ to 700 ℃,the char yield decreased from 72.94% to 39.79%;the char becomes more carbonaceous,this lead to a increase in LHV from 29.19 MJ/kg to 31.62 MJ/kg,C content of the char significantly increased from 65.93% to 84.89%;with increasing in pyrolysis temperature from 300 ℃ to 600 ℃,specific surface area of the char increased from 0.47 m2/g to 13.63 m2/g,iodine adsorption of the char increased from 185.51 mg/g to 320.64 mg/g,while with further increasing of temperature,specific surface area of the char and iodine adsorption of the char declined rapidly.Therefore,the effect of pyrolysis temperature on the improvement of quality and adsorption of the char is significant,while adsorption of the char will reduces at excessive temperature.

ligninpyrolysischaradsorption

蒋恩臣、陈爱慧、秦丽元、赵晨希、罗立娜

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东北农业大学工程学院,黑龙江哈尔滨 150030

木质素 热解 焦炭 吸附特性

国家科技支撑课题中国博士后科学基金黑龙江省青年科学基金黑龙江省教育厅科学技术研究项目黑龙江省博士后基金东北农业大学博士启动基金东北农业大学青年才俊项目

2014BAD06B042012M520698QC201504912531002LBH-Z120312012RCB9714QC35

2015

可再生能源
辽宁省能源研究所 中国农村能源行业协会 中国资源综合利用协会可再生能源专委会 中国生物质能技术开发中心 辽宁省太阳能学会

可再生能源

CSTPCD北大核心
影响因子:0.605
ISSN:1671-5292
年,卷(期):2015.33(7)
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