首页|电流密度、温度、阴极孔隙率和N2溶解度因子对Li-N2电池放电性能的影响

电流密度、温度、阴极孔隙率和N2溶解度因子对Li-N2电池放电性能的影响

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Li-N2电池是一种具有电化学固氮功能的新型储能系统,文章利用有限元软件COMSOL耦合多物理场建立的电化学模型能揭示各因素对其放电性能的影响。模拟结果表明:放电电流密度、温度、阴极孔隙率和电解液中的N2溶解度因子对Li-N2电池的放电性能均有影响;较大的放电电流密度会降低该电池的电压和容量;阴极孔隙率和电解液中的N2溶解度因子是影响该电池电压和容量的关键性因素,提高阴极孔隙率和电解液中的N2溶解度因子均能增加该电池的电压和容量;电池放电的平台电压随温度升高而升高,但放电容量几乎不受温度影响。
Li-N2 battery discharge performances affected by discharge current density,temperature,cathode porosity and N2 solubility factor
Li-N2 battery is a new type of energy storage system with the function of electrochemical nitrogen fixation,and the electrochemical model established in the article used finite element software COMSOL coupled with multi-physics field can reveal the influence of various factors on its discharge performance.The simulation results show that;the discharge current density,temperature,cathode porosity and N2 solubility factor in the electrolyte have an effect on the discharge performance of Li-N2 battery;a larger discharge current density will reduce the voltage and capacity of the battery;cathode porosity and N2 solubility factor in the electrolyte are the key factors that affect the voltage and capacity of the battery,and increasing the cathode porosity and N2 solubility factor in the electrolyte can increase the voltage and capacity of the battery;With the temperature rising,the voltage of the discharge platform of the battery increases,but the discharge capacity is almost unaffected by temperature.

Li-N2 batteriesfinite element analysisCOMSOLdischarge process

赵旭东、薛红涛、汤富领

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兰州理工大学材料科学与工程学院,甘肃兰州 730050

兰州理工大学有色金属先进加工与再利用国家重点实验室,甘肃兰州 730050

Li-N2电池 有限元分析 COMSOL 放电过程

国家自然科学基金

11764027

2024

可再生能源
辽宁省能源研究所 中国农村能源行业协会 中国资源综合利用协会可再生能源专委会 中国生物质能技术开发中心 辽宁省太阳能学会

可再生能源

CSTPCD北大核心
影响因子:0.605
ISSN:1671-5292
年,卷(期):2024.42(1)
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