可再生能源2024,Vol.42Issue(2) :182-188.

膨胀蛭石基复合相变储热材料的制备及性能研究

Preparation and properties of expanded vermiculite-based composites

白瑞雪 刘松阳 王梦晴 高卫
可再生能源2024,Vol.42Issue(2) :182-188.

膨胀蛭石基复合相变储热材料的制备及性能研究

Preparation and properties of expanded vermiculite-based composites

白瑞雪 1刘松阳 1王梦晴 1高卫1
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作者信息

  • 1. 辽宁石油化工大学 土木工程学院, 辽宁 抚顺 113001
  • 折叠

摘要

文章以癸酸-棕榈酸(CA-PA)二元共晶物作为相变材料,膨胀蛭石(EVM)作为支撑材料,采用真空浸渍法制备癸酸-棕榈酸/膨胀蛭石复合相变储热材料(CA-PA/EVM).通过FT-IR,DSC,TG,热循环等测试方法对癸酸-棕榈酸/膨胀蛭石复合相变储热材料的化学兼容性、储热性能、热稳定性及可靠性进行系统研究.结果表明:膨胀蛭石通过物理作用吸附癸酸-棕榈酸二元共晶物至其层状孔隙结构,且二者化学兼容性良好;癸酸-棕榈酸/膨胀蛭石复合相变储热材料的融化和凝固相变温度分别 23.61,20.41℃,熔化和凝固相变潜热分别为67.22,64.87 J/g;膨胀蛭石中癸酸-棕榈酸的封装量可达 52.22%,在工作温度下具有良好的热稳定性;癸酸-棕榈酸/膨胀蛭石复合相变储热材料经过 100次热循环后仍保持良好的热可靠性,在建筑节能领域具有广阔的应用前景.

Abstract

In this study,the Capric-palmitic acid(CA-PA)binary eutectic PCM was vacuum impregnated into the expanded vermiculite(EVM)to prepare CA-PA/EVM composite phase change thermal storage material.FT-IR,DSC,TG,and thermal cycling were used to assess the chemical compatibility,heat storage performance,thermal stability,and thermal reliability of CA-PA/EVM.The results showed that CA-PA was stably loaded in the layered pores of EVM through physical interaction,and CA-PA/EVM had excellent chemical compatibility.The Melting and solidification phase transition temperatures of CA-PA/EVM were 23.61 and 20.41℃,respectively.The latent heat of melting and solidification phase transition were 67.22 and 64.87 J/g,respectively.The amount of CA-PA encapsulated in EVM could reach 52.22%,and it had favorable thermal stability at working temperature.In addition,the CA-PA/EVM maintained great thermal reliability after 100 thermal cycles,indicating its potential application in the building energy conservation field.

关键词

癸酸-棕榈酸/膨胀蛭石/复合相变储热材料/建筑节能

Key words

capric acid-palmitic acid/expanded vermiculite/composite phase change energy storage material/building energy conservation

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基金项目

辽宁省教育厅面上项目(LJKZ0405)

出版年

2024
可再生能源
辽宁省能源研究所 中国农村能源行业协会 中国资源综合利用协会可再生能源专委会 中国生物质能技术开发中心 辽宁省太阳能学会

可再生能源

CSTPCD北大核心
影响因子:0.605
ISSN:1671-5292
被引量2
参考文献量7
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