首页|坝上地区莜麦秸秆热解特性研究

坝上地区莜麦秸秆热解特性研究

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为实现高寒坝上地区农作物秸秆高效清洁燃烧,文章选取典型莜麦秸秆作为研究对象,通过混合气体模拟烟气燃烧过程中的热解气氛环境,采用热重分析仪研究空气和N2,CO2,O2 不同比例组成的混合气体氛围下热失重特性以及升温速率对其影响,采用AKTS软件进行动力学分析。结果表明:莜麦秸秆热解过程可分为干燥(30~140℃)、挥发(140~370℃)、炭化(370~900℃)3 个阶段;气体氛围主要影响热解的炭化阶段,对干燥和挥发阶段影响较小;升温速率影响挥发和炭化阶段,升温速率越快,反应速率越大;当热解气氛为 15%O2-5%CO2-80%N2 混合气体(气体 2)时,热解过程所需活化能最少,平均活化能为 139。86 kJ/mol。研究结果可为高寒坝上地区生物质秸秆能源化利用提供一定理论依据。
Pyrolysis characteristics of naked oats straw in Bashang area
In order to achieve high efficiency and clean combustion of crop straw in Bashang area,typical naked oats straw was selected as the research object to analyze the pyrolysis characteristics.The pyrolysis atmosphere environment in the combustion process was created by simulating flue gas with mixed gases.The thermogravimetric analyzer was used to study the thermogravimetric characteristics and the influence of temperature rise rate on the mixed gas atmosphere composed of air and N2,CO2,and O2 in different proportions.The AKTS software was used for kinetic analysis.The results showed that:the pyrolysis process of naked oats straw was divided into three stages,which were drying stages(30~140℃),volatilization stages(140~370℃),carbonization stages(370~900℃).Gas atmosphere mainly affected the pyrolysis of carbonization stage,drying and volatilization stage had little effect,heating rate affects volatilization and carbonization stage,the faster the heating rate,the greater the reaction rate.When the pyrolysis atmosphere was 15%O2-5%CO2-80%N2 mixed gas(gas 2),the activation energy required for pyrolysis process was the least,and the average activation energy was 139.86 kJ/mol.The results provided a certain theoretical basis for the energy utilization of biomass straw in the alpine Bashang area.

Bashang areanaked oats strawpyrolysis characteristicsactivation energy

刘联胜、梁小虎、王冬计、张晓宇、黄亚龙

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河北工业大学 能源与环境工程学院,天津 300401

河北省热科学与能源清洁利用技术重点实验室,天津 300401

天津城建大学 能源与安全工程学院,天津 300384

坝上地区 莜麦秸秆 热解特性 活化能

天津市教委科研计划项目天津市科技计划项目

2023KJ21819ZXBTSN00220

2024

可再生能源
辽宁省能源研究所 中国农村能源行业协会 中国资源综合利用协会可再生能源专委会 中国生物质能技术开发中心 辽宁省太阳能学会

可再生能源

CSTPCD北大核心
影响因子:0.605
ISSN:1671-5292
年,卷(期):2024.42(3)
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