首页|C6F12O与CO2/N2对变压器油分解气体火焰及HF的抑制作用

C6F12O与CO2/N2对变压器油分解气体火焰及HF的抑制作用

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变压器油分解为可燃气体燃烧具有高危险性,新型的环保灭火剂C6F12O抗复燃性差会产生有害产物HF.为此研究了N2或CO2的加入对C6F12O扑灭变压器油分解气体火焰的灭火性能及有害产物HF的影响,采用化学动力学方法计算了不同当量比与混合比下C6F12O混合物对变压器油分解气体火焰绝热燃烧温度、活性自由基浓度的作用效果,分析了HF浓度变化及生成路径变化规律.理论计算表明N2或CO2与C6F12O具有良好的物理化学协同灭火作用,且能抑制有害产物HF的生成.研究结果为C6F12O灭火剂在电气火灾应用提供了理论依据和数据参考.
Inhibition Effect of C6F12O and CO2/N2 on Transformer Oil De-Composition Gas Flame and HF
Transformer oil de-composition into combustible gas combustion has a high risk.The new environmental protection fire extinguishing agent C6F12O has poor reignition resistance and will produce harmful product HF.Therefore,this paper studies the ef-fects of N2 or CO2 addition on the fire extinguishing performance of C6F12O extinguishing the flame with transformer oil discharges gas and the harmful product HF.Chemical dynamics method is used to calculate the effects of C6F12O mixture on adiabatic combus-tion temperature and active free radical concentration of transformer oil de-composition gas flame under different equivalent ratios and mixing ratios.The variation law of HF concentration and generation path are analyzed.Theoretical calculation results show that N2 or CO2 and C6F12O have good physicochemical collaborative fire extinguishing effect and can inhibit the formation of harmful product HF.The research results of this paper provide theoretical basis and data reference for the application of C6F12O fire extinguishing agent in electrical fire.

C6F12Otransformer oilchemical reactionreaction kineticsadiabatic combustion temperature

田双双、李哲、张晓星、李晓涵、王家浩

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湖北工业大学新能源及电网装备安全监测湖北省工程研究中心,武汉 430070

襄阳湖北工业大学产业研究院,湖北 襄阳 441100

C6F12O 变压器油 化学反应 反应动力学 绝热燃烧温度

国家自然科学基金湖北省自然科学基金

522771442021CFA025

2024

南方电网技术
南方电网科学研究所有限责任公司

南方电网技术

CSTPCD北大核心
影响因子:1.42
ISSN:1674-0629
年,卷(期):2024.18(4)
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