首页|粉煤灰-锂渣基发泡陶瓷的制备及性能研究

粉煤灰-锂渣基发泡陶瓷的制备及性能研究

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为制备低成本兼具高孔隙率与高压缩强度的发泡陶瓷,以粉煤灰、锂渣、长石、滑石和碳化硅为原料,经1 180、1 200、1 220、1 240℃分别保温10、20、40、60 min烧结制备发泡陶瓷试样.主要研究了锂渣的掺量(质量分数分别为0、10%、20%、30%)对试样物相组成、显微结构、孔隙率及压缩强度的影响.结果表明:1)随锂渣掺量的增加,发泡陶瓷的孔隙率增加,体积密度降低,压缩强度波动;2)锂渣中丰富的钙、硫成分,可发挥助熔剂和发泡剂作用,降低烧结温度,提高发泡陶瓷的孔隙率,改善气孔圆整度,提高压缩强度;3)当锂渣掺量为20%(w)时,经1 220℃保温20~40 min烧结所得发泡陶瓷的体积密度为0.32~0.40 g·cm-3,孔隙率为84.4%~87.6%,压缩强度为 1.51~2.35 MPa.
Preparation and properties of foamed ceramics based on fly ash and lithium slag
In order to prepare low-cost foamed ceramics with high porosity and compressive strength,foamed ceramics samples were prepared at different temperatures(1 180,1 200,1 220 and 1 240 ℃)for different durations(10,20,40 and 60 min),using fly ash,lithium slag,feldspar,talcum and silicon carbide as raw materials.The effects of the lithium slag addition(0,10%,20%and 30%,by mass)on the phase composition,microstructure,porosity,and compressive strength of the samples were studied.The results show that:(1)with the increase of the lithium slag addition,the porosity of the samples increases;the bulk density decreases;the compressive strength fluctuates;(2)the calcium and sulfur components in lithium slag work as the fluxing agent and foaming agent,which reduces the sintering temperature,increases the porosity,improves the pore roundness and enhances the compressive strength;(3)when the lithium slag addition is 20%,for the sample obtained at 1 220 ℃ for 20-40 min,the bulk density is 0.32-0.40 g·cm-3,the porosity is 84.4%-87.6%and the compressive strength is 1.51-2.35 MPa.

fly ashlithium slagfoamed ceramicsolid waste coordinationcompressive strengthporosity

常星岚、陈瑶姬、顾雅洁、孙盛睿、孙科、廖达琛、刘阳桥、奚爽、李小红

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浙江天地环保科技股份有限公司 浙江杭州 311199

中国科学院 上海硅酸盐研究所 上海 200050

粉煤灰 锂渣 发泡陶瓷 固废协同 压缩强度 孔隙率

国家自然科学基金资助项目国家自然科学基金资助项目浙江省能源集团有限公司科技项目浙江天地环保科技股份有限公司科技项目

5187864761574148ZNJK-2022-065TD-KJ-22-007

2024

耐火材料
中钢集团洛阳耐火材料研究院有限公司

耐火材料

北大核心
影响因子:0.808
ISSN:1001-1935
年,卷(期):2024.58(1)
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