耐火材料2024,Vol.58Issue(1) :1-7.DOI:10.3969/j.issn.1001-1935.2024.01.001

粉煤灰-锂渣基发泡陶瓷的制备及性能研究

Preparation and properties of foamed ceramics based on fly ash and lithium slag

常星岚 陈瑶姬 顾雅洁 孙盛睿 孙科 廖达琛 刘阳桥 奚爽 李小红
耐火材料2024,Vol.58Issue(1) :1-7.DOI:10.3969/j.issn.1001-1935.2024.01.001

粉煤灰-锂渣基发泡陶瓷的制备及性能研究

Preparation and properties of foamed ceramics based on fly ash and lithium slag

常星岚 1陈瑶姬 1顾雅洁 1孙盛睿 2孙科 1廖达琛 1刘阳桥 2奚爽 1李小红2
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作者信息

  • 1. 浙江天地环保科技股份有限公司 浙江杭州 311199
  • 2. 中国科学院 上海硅酸盐研究所 上海 200050
  • 折叠

摘要

为制备低成本兼具高孔隙率与高压缩强度的发泡陶瓷,以粉煤灰、锂渣、长石、滑石和碳化硅为原料,经1 180、1 200、1 220、1 240℃分别保温10、20、40、60 min烧结制备发泡陶瓷试样.主要研究了锂渣的掺量(质量分数分别为0、10%、20%、30%)对试样物相组成、显微结构、孔隙率及压缩强度的影响.结果表明:1)随锂渣掺量的增加,发泡陶瓷的孔隙率增加,体积密度降低,压缩强度波动;2)锂渣中丰富的钙、硫成分,可发挥助熔剂和发泡剂作用,降低烧结温度,提高发泡陶瓷的孔隙率,改善气孔圆整度,提高压缩强度;3)当锂渣掺量为20%(w)时,经1 220℃保温20~40 min烧结所得发泡陶瓷的体积密度为0.32~0.40 g·cm-3,孔隙率为84.4%~87.6%,压缩强度为 1.51~2.35 MPa.

Abstract

In order to prepare low-cost foamed ceramics with high porosity and compressive strength,foamed ceramics samples were prepared at different temperatures(1 180,1 200,1 220 and 1 240 ℃)for different durations(10,20,40 and 60 min),using fly ash,lithium slag,feldspar,talcum and silicon carbide as raw materials.The effects of the lithium slag addition(0,10%,20%and 30%,by mass)on the phase composition,microstructure,porosity,and compressive strength of the samples were studied.The results show that:(1)with the increase of the lithium slag addition,the porosity of the samples increases;the bulk density decreases;the compressive strength fluctuates;(2)the calcium and sulfur components in lithium slag work as the fluxing agent and foaming agent,which reduces the sintering temperature,increases the porosity,improves the pore roundness and enhances the compressive strength;(3)when the lithium slag addition is 20%,for the sample obtained at 1 220 ℃ for 20-40 min,the bulk density is 0.32-0.40 g·cm-3,the porosity is 84.4%-87.6%and the compressive strength is 1.51-2.35 MPa.

关键词

粉煤灰/锂渣/发泡陶瓷/固废协同/压缩强度/孔隙率

Key words

fly ash/lithium slag/foamed ceramic/solid waste coordination/compressive strength/porosity

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基金项目

国家自然科学基金资助项目(51878647)

国家自然科学基金资助项目(61574148)

浙江省能源集团有限公司科技项目(ZNJK-2022-065)

浙江天地环保科技股份有限公司科技项目(TD-KJ-22-007)

出版年

2024
耐火材料
中钢集团洛阳耐火材料研究院有限公司

耐火材料

北大核心
影响因子:0.808
ISSN:1001-1935
参考文献量15
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