耐火材料2024,Vol.58Issue(1) :13-18.DOI:10.3969/j.issn.1001-1935.2024.01.003

不同碱度渣对刚玉-尖晶石浇注料的侵蚀行为研究

Corrosion behavior of slags with different basicities to corundum spinel castables

杨宗源 王景然 王桐 张锦化 韩兵强 倪月娥 柯昌明
耐火材料2024,Vol.58Issue(1) :13-18.DOI:10.3969/j.issn.1001-1935.2024.01.003

不同碱度渣对刚玉-尖晶石浇注料的侵蚀行为研究

Corrosion behavior of slags with different basicities to corundum spinel castables

杨宗源 1王景然 1王桐 1张锦化 1韩兵强 1倪月娥 1柯昌明1
扫码查看

作者信息

  • 1. 武汉科技大学省部共建耐火材料与冶金国家重点实验室 湖北武汉 430081
  • 折叠

摘要

浇注料的抗渣侵蚀性能与钢渣的碱度密切相关.以烧结刚玉、缺陷尖晶石微粉、活性α-Al2O3微粉、电熔镁砂细粉和铝酸钙水泥(Secar71)为主要原料,制备了刚玉-尖晶石浇注料,采用静态坩埚法于1600 ℃保温3 h进行抗渣试验,并用热力学模拟计算了液相量和液相组成,研究了刚玉-尖晶石浇注料对3种不同碱度渣(1.6、2.3和7.6)的抗渣侵蚀性能.结果表明:刚玉-尖晶石浇注料在高碱度渣中溶解能力有限,在熔渣-耐火材料界面极易形成尖晶石固溶体和六铝酸钙等高熔点物相,形成致密层阻挡熔渣渗透和侵蚀.而其在低碱度渣中溶解度较高,在浇注料-熔渣达到较高反应程度时,才开始形成尖晶石固溶体和六铝酸钙等高温相,无法形成有效的致密层阻止熔渣对浇注料的侵蚀和渗透.因此,刚玉-尖晶石浇注料对高碱度渣抗渣侵蚀能力较强,对低碱度渣抗渣侵蚀能力较弱.

Abstract

The slag corrosion resistance of castables is closely related to the basicity of steel slag.Sintered corundum,defective spinel micropowder,active α-Al2O3 micropowder,fused magnesia fine powder,and calcium aluminate cement(Secar 71)were used as the main raw materials to prepare corundum spinel castables.The slag resistance test was conducted using the static crucible method at 1 600 ℃ for 3 h,and the amount and composition of the liquid phase were thermodynamically simulated.The slag corrosion re-sistance of the corundum spinel castables against the three slags with different basicities(1.6,2.3,and 7.6)was studied.The results show that the high basicity slag has limited solubility to corundum spinel castables;it is easy to form high melting point phases such as spinel solid solution and calcium hexalumi-nate at the interface between slag and castables,forming a dense layer to prevent slag penetration and corrosion;the solubility of corundum spinel castables is high in low basicity slag;spinel solid solution,calci-um hexaluminate or other high temperature phases can't form until the slag and the castables reach a high reaction degree,thus an effective dense layer can't form to prevent the corrosion and penetration of slag into the castables.Therefore,corundum spinel castables have better slag corrosion resistance to high ba-sicity slags than low basicity slags.

关键词

刚玉-尖晶石浇注料/碱度/抗渣侵蚀性能/热力学模拟

Key words

corundum spinel castables/basicity/slag resistance/thermodynamic simulation

引用本文复制引用

基金项目

国家自然科学基金资助项目(51802235)

湖北省科学技术厅2023年科技人才服务企业项目(2023DJC087)

出版年

2024
耐火材料
中钢集团洛阳耐火材料研究院有限公司

耐火材料

北大核心
影响因子:0.808
ISSN:1001-1935
参考文献量11
段落导航相关论文