首页|固废资源合成堇青石工艺及其性能研究

固废资源合成堇青石工艺及其性能研究

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为了合理利用固废资源、缓解资源紧张,根据堇青石的化学组成,以质量分数分别为12%的电熔镁砂收尘粉、40%的电熔刚玉收尘粉、48%的石英尾砂为原料,分别在1 320、1 350、1 380、1 390、1 400、1 410 ℃保温3 h煅烧,制备堇青石质耐火原料,研究了煅烧温度对堇青石试样相组成、显微结构、物理性能等的影响.结果表明:在1 390 ℃之前,镁铝尖晶石和方石英逐渐反应生成堇青石直至方石英相完全消除,当煅烧温度达到1 390℃时,试样中的堇青石相含量达94%(w),次晶相为镁铝尖晶石,此时试样的热膨胀系数最低,为3.2 × 10-6℃-1,体积密度较低,为1.85 g·cm-3,热导率较低,为1.279 W·(m·K)-1,显微结构较致密,综合性能最优.
Synthesis technology and properties of cordierite from solid waste resources
To effectively utilize solid waste resources and relieve resource constraints,cordierite refractory raw materials were prepared according to the chemical composition of cordierite,using 12 mass%fused magnesia dust powder,40 mass%fused corundum dust powder and 48 mass%quartz tailings as starting materials,calcining at 1 320,1 350,1 380,1 390,1 400 and 1 410 ℃ for 3 h,respectively.The effects of the calcination temperature on the phase composition,microstructure and physical properties of the cordierite specimens were studied.The results show that below 1 390 ℃,magnesium aluminate spinel and cristobalite gradually react to form cordierite until cristobalite is completely exhausted;when the calcination tempera-ture reaches 1 390 ℃,the cristobalite content in the sample reaches 94 mass%,and the secondary crystal phase is magnesium aluminate spinel;at this time,the sample has the optimal comprehensive perform-ance:the lowest thermal expansion coefficient of 3.2 x 10-6 ℃-1,a low bulk density of 1.85 g·cm-3,a low thermal conductivity of 1.279 W·(m·K)-1and dense microstructure.

fused corundum dust powderfused magnesia dust powderquartz tailingssolid phase synthe-sis methodcordierite

谭栖桐、赵惠忠、余俊、张寒、谈利强

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武汉科技大学省部共建耐火材料与冶金国家重点实验室 湖北武汉 430081

浙江父子岭特种耐火材料有限公司 浙江湖州 313108

电熔刚玉收尘粉 电熔镁砂收尘粉 石英尾砂 固相合成法 堇青石

辽宁省科技攻关计划

2022JH1/1080005

2024

耐火材料
中钢集团洛阳耐火材料研究院有限公司

耐火材料

北大核心
影响因子:0.808
ISSN:1001-1935
年,卷(期):2024.58(3)