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硅溶胶-酚醛树脂共结合Al2O3-SiC-C砖性能研究

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为了缓解酚醛树脂碳化引起的Al2O3-SiC-C砖组织结构劣化,提升Al2O3-SiC-C砖的力学性能和抗渣性能,以粒度分别为5~3、3~1和≤1 mm的高铝矾土为骨料,以电熔白刚玉(≤ 0.045 mm)、SiC(≤0.075 mm)、α-Al2O3微粉和鳞片石墨(≤0.15 mm)等为基质,以热固性酚醛树脂和硅溶胶为结合剂,制备了硅溶胶-酚醛树脂共结合Al2O3-SiC-C砖.在酚醛树脂外加量为4.5%(w)的基础上,探究了硅溶胶的加入量(外加质量分数分别为0、0.45%、0.90%和1.35%)对Al2O3-SiC-C砖常温力学性能、高温力学性能和抗渣性能的影响.结果表明:引入适量硅溶胶可以有效提升Al2O3-SiC-C砖的力学性能及抗渣性能,当硅溶胶加入量为0.45%(w)时,试样具有优异的常温、高温力学性能及抗渣性能.
Properties of silica sol-phenolic resin co-bonded Al2O3-SiC-C bricks
To mitigate the structural deterioration of Al2O3-SiC-C bricks induced by phenolic resin carboni-zation and enhance their mechanical properties and slag resistance,silica sol-phenolic resin co-bonded Al2O3-SiC-C bricks were prepared using bauxite(5-3,3-1 and ≤1 mm)as aggregates,white fused co-rundum(≤0.045 mm),SiC(≤0.075 mm),α-Al2O3 micropowder and flake graphite(≤0.15 mm)as the matrix,and thermosetting phenolic resin and silica sol as the binders.Based on the extra addition of 4.5 mass%phenolic resin,the effects of the silica sol extra addition(mass fractions of 0,0.45%,0.90%and 1.35%,respectively)on the cold and hot mechanical properties and slag resistance of the bricks were investigated.The results show that an appropriate addition of silica sol can effectively improve the mechani-cal properties and slag resistance of the Al2O3-SiC-C bricks,and the specimen with 0.45%silica sol per-forms excellent cold and hot mechanical properties and slag resistance.

silica solphenolic resinAl2O3-SiC-C bricks

吕宝栋、高东升、鞠茂奇、杨帆

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鞍钢集团朝阳钢铁有限公司炼铁厂 辽宁朝阳 122000

武汉科技大学 湖北武汉 430081

中冶武汉冶金建筑研究院有限公司 湖北武汉 430081

硅溶胶 酚醛树脂 Al2O3-SiC-C砖

2024

耐火材料
中钢集团洛阳耐火材料研究院有限公司

耐火材料

北大核心
影响因子:0.808
ISSN:1001-1935
年,卷(期):2024.58(3)