首页|高能等离子喷涂垂直裂纹氧化锆热障涂层工艺及结合性能研究

高能等离子喷涂垂直裂纹氧化锆热障涂层工艺及结合性能研究

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为延长氧化钇稳定氧化锆热障涂层的使用寿命,通过高能等离子喷涂设备,以HS188合金为基体,NiCrAlY粉(打底层,d50=106 µm)和氧化钇稳定的氧化锆粉(YSZ,d50=50 μm)为喷涂料,采用递进式的探索方法,通过调整枪基距(85、95、105和115 mm)和冷却方式(后风冷、后风冷+枪冷、前风冷、前风冷+枪冷)来控制涂层的组织结构,并采用拉拔法评价NiCrAlY+YSZ涂层的结合强度.结果表明:在枪基距较远以及冷却速率较低的情况下,因试样表面瞬热温度较低和激冷不足,涂层难以形成垂直裂纹结构.然而,在瞬热温度达到要求,风冷速率过度的情况下,会出现喷涂颗粒未熔的现象.当枪基距为85 mm,冷却方式为前风冷时,在HS188合金上获得了垂直裂纹形貌的热障陶瓷涂层,同时涂层的垂直裂纹密度适中,结合强度最高,韧性也最好.
Process and bonding performance of ZrO2 thermal barrier coatings with vertical cracks by high energy plas-ma spraying
In order to prolong the service life of ZrO2 thermal barrier coatings,HS188 alloy was used as the substrate,and NiCrAIY powder(base layer,d50=106 μm)and yttria stabilized zirconia(YSZ,d50=50 μm)were employed as sprayed feeder to prepare NiCrAIY+YSZ thermal barrier coatings using high-energy plasma spraying equipment with a progressive exploration method.The microstructure of the coatings was controlled by adjusting the stand-off distance(85,95,105 and 115 mm)and air-cooling manner(rear air cooling,rear air cooling+gun cooling,front air cooling,and front air cooling+gun cooling).The bonding strength of the coatings was evaluated by the drawing method.The results indicate that under the condi-tions of long stand-off distance and low cooling rate,it is difficult for the coatings to form a vertical crack structure due to the low instantaneous heating temperature and insufficient quenching on the sample sur-face.However,when the instantaneous heating temperature reaches the critical value and the air cooling rate is excessive,un-melted spray particles exist.When the stand-off distance is 85 mm and the cooling method is front air cooling,a thermal barrier ceramic coating with vertical crack morphology was obtained on HS188 alloy.Simultaneously,it has a moderate density of vertical cracks,the highest bonding strength and the best toughness.

high-energy plasma sprayingthermal barrier coatingNiCrAIYzirconiaair coolingstand-off distance

刘保侠、张盟、周绪强、牛云松、黄迪、杨沁乾、鲍泽斌、朱圣龙

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国家管网集团北方管道有限责任公司 河北廊坊 065000

北京科技大学新金属材料国家重点实验室 北京 100083

中国科学院金属研究所师昌绪先进材料创新中心 辽宁沈阳 110016

高能等离子喷涂 热障涂层 NiCrAlY 氧化锆 风冷 枪基距

国家自然科学青年基金资助项目

51701223

2024

耐火材料
中钢集团洛阳耐火材料研究院有限公司

耐火材料

北大核心
影响因子:0.808
ISSN:1001-1935
年,卷(期):2024.58(4)