首页|菱镁矿尾矿细粉对MgO-SiO2质浇注料性能的影响

菱镁矿尾矿细粉对MgO-SiO2质浇注料性能的影响

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为提高MgO-SiO2质浇注料的烧结性能,缩短烧结时间并降低生产成本,以电熔镁砂、SiO2微粉、板状刚玉细粉、碳化硅细粉和菱镁矿尾矿细粉为主要原料,制备了 MgO-SiO2质浇注料.研究了菱镁矿尾矿细粉加入量(加入质量分数分别为0、2%、4%、6%和8%)对浇注料流动性、显微结构以及力学性能的影响.结果表明:1)菱镁矿尾矿细粉分解生成的高活性MgO与SiO2微粉原位反应促进了镁橄榄石颈部连接的形成,且原料中镁砂与刚玉细粉的原位反应促进了尖晶石颈部连接的形成;2)菱镁矿尾矿中的CaO和SiO2等杂质在高温下与MgO反应生成了低熔点钙镁橄榄石相,在1 500℃时以液相存在,促进了试样的烧结;3)添加4%(w)的菱镁矿尾矿细粉时,浇注料的综合性能最佳.
Effect of magnesite tailings powder on properties of MgO-SiO2 castables
In order to improve the sintering performance of MgO-SiO2 castables,shorten the sintering time and reduce the production cost,MgO-SiO2 castables were prepared using fused magnesia,silica mi-cropowder,tabular corundum powder,silicon carbide powder,and magnesite tailings powder as the main raw materials.The effects of the magnesite tailings powder addition(0,2%,4%,6%and 8%,by mass,re-spectively)on the fluidity,microstructure and mechanical properties of the castables were studied.The re-sults show that:1)the in-situ reaction between highly active MgO generated by the decomposition of mag-nesite tailings powder and silica micropowder promotes the formation of forsterite neck connection,and the in-situ reaction between magnesia and corundum powder in raw materials promotes the formation of spinel neck connection;2)impurities such as CaO and SiO2 in magnesite tailings react with MgO at high tempera-tures to form a low melting point calcium magnesium olivine phase,which exists as a liquid phase at 1 500 ℃,promoting the sintering of the sample;3)when 4%magnesite tailings powder is added,the com-prehensive performance of the castable is the best.

MgO-SiO2 castablesmagnesite tailingsmicrostructuremechanical properties

张晓存、聂建华、梁永和、高东升、鄢文、尹玉成

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武汉科技大学省部共建耐火材料与冶金国家重点实验室 湖北武汉 430081

钢铁工业耐火材料新技术国际合作联合实验室 湖北武汉 430081

MgO-SiO2质浇注料 菱镁矿尾矿 显微结构 力学性能

国家自然科学基金联合基金重点项目

U21A2058

2024

耐火材料
中钢集团洛阳耐火材料研究院有限公司

耐火材料

北大核心
影响因子:0.808
ISSN:1001-1935
年,卷(期):2024.58(5)