金陵科技学院学报2024,Vol.40Issue(1) :63-71.DOI:10.16515/j.cnki.32-1722/n.2024.01.008

石墨相氮化碳负载钴的制备及其可见光催化性能

Preparation and Visible-Light-Driven Catalytic Performance of Co/g-C3N4

汪园园 王梦 贾仕骏 丁世强 朱姚先
金陵科技学院学报2024,Vol.40Issue(1) :63-71.DOI:10.16515/j.cnki.32-1722/n.2024.01.008

石墨相氮化碳负载钴的制备及其可见光催化性能

Preparation and Visible-Light-Driven Catalytic Performance of Co/g-C3N4

汪园园 1王梦 1贾仕骏 1丁世强 1朱姚先1
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作者信息

  • 1. 金陵科技学院材料工程学院,江苏 南京 211169
  • 折叠

摘要

使用金属负载的方式对石墨相氮化碳进行改性,得到石墨相氮化碳负载钴光催化剂(Co/g-C3N4).采用电子显微镜、X射线衍射仪、X射线光电子能谱仪、紫外可见漫反射光谱、光致发光光谱以及光电化学测试对制备的催化剂进行了表征.通过光催化评价系统探究了 Co/g-C3N4光催化降解盐酸四环素(TC)的效果,以及不同催化剂投入量、污染物浓度等因素对Co/g-C3N4光催化降解TC的影响及机理.结果表明,钴金属的负载使得石墨相氮化碳电子-空穴对的分离效率进一步提高,催化剂的光催化活性得到改善,且钴负载后的石墨相氮化碳的晶体结构与表面形貌并未发生改变;1%Co/g-C3N4在120 min内可见光下对TC去除率可达95.68%,TC去除速率是纯g-C3N4催化下的2.3倍,5次催化循环后对TC的光催化降解效率仍保持在80%以上,有着良好的稳定性和可回收性;光催化反应中空穴和羟基自由基为主要活性物质.

Abstract

Graphite-phase carbon nitride was modified by metal loading to obtain cobalt photo-catalyst supported on graphite-phase carbon nitride(Co/g-C3N4).The prepared catalysts were characterized using electron microscopy,X-ray diffraction,X-ray photoelectron spectroscopy,UV-visible diffuse reflectance spectroscopy,photoluminescence spectroscopy,and photoelec-trochemical testing.The effectiveness of photocatalytic degradation of tetracycline hydrochlo-ride(TC)over Co/g-C3N4 was investigated through a photocatalytic evaluation system,and so did the effects and the mechanism of different catalyst inputs,pollutant concentrations,and other factors on the photocatalytic degradation of TC by Co/g-C3N4.The results showed that the loading of metal cobalt further improved the separation efficiency of electron-hole pairs in graphite-phase carbon nitride,and enhanced the photocatalytic activity of the catalyst.Further-more,it did not change the crystal structure and surface morphology of graphite-phase carbon nitride after cobalt loading.The removal quantity of TC over 1%Co/g-C3N4 under visible light can reach 95.68%within 120 minutes.The removal rate of TC is 2.3 times that of pure g-C3N4 Catalysis.The photocatalytic degradation efficiency of TC after five catalytic cycles was above 80%,indicating good stability and recyclability.It was found that holes and hydroxyl radicals were the main active sub-stances in the photocatalytic reaction.

关键词

石墨相氮化碳/钴负载/光催化降解/盐酸四环素

Key words

graphite-phase carbon nitride/cobalt loading/photocatalytic degradation/tetracy-cline hydrochloride

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基金项目

国家自然科学基金青年基金(22206065)

金陵科技学院高层次人才科研启动基金(jitb-202024)

出版年

2024
金陵科技学院学报
金陵科技学院

金陵科技学院学报

影响因子:0.5
ISSN:1672-755X
参考文献量3
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