首页|生物炭对水中对乙酰氨基酚的去除性能及机理研究

生物炭对水中对乙酰氨基酚的去除性能及机理研究

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生物炭在水中非甾体类抗炎药(NSAIDs)吸附去除方面具有良好的应用前景.目前关于生物炭对NSAIDs去除过程和机理的报道较有限,尤其对于动态吸附的研究非常缺乏.以对乙酰氨基酚为研究对象,分别通过批次吸附实验和固定床吸附实验,研究了商业生物炭对其静态和动态吸附过程.伪二阶动力学模型和Elovich均能较好地拟合吸附动力学曲线,Langmuir模型对吸附等温线的拟合程度大于Freundlich模型,吸附容量拟合值为 131.578 mg/g.固定床动态吸附实验表明生物炭添加量和流速均可显著影响其动态吸附过程,Thomas模型、Yoon-Nelson模型、Clark模型和BDST模型均可对动态吸附过程进行较好的拟合和预测.研究表明,生物炭在大规模应用于水中对乙酰氨基酚的去除上具有良好的前景.
Removal of Acetaminophen by Biochar from Aqueous Environment:Performance and Mechanisms
Biochar is one of the most promising materials for non-steroidal anti-inflammatory drugs(NSAIDs)removal from aqueous environment.However,the relative study is far from complete and involved mechanisms are unclear,especially about the dynamic adsorption process.Batch adsorption and fixed-bed column experiments are conducted to investigate the removal of acetaminophen(AP)from aqueous environment by commercial biochar.The sorption kinetics are well fitted with Pseudo-second-order model and Elovich model.The adsorption isotherm could be better described by Langmuir model than Freundlich model,and the Langmuir maximum capacity is 131.578 mg/g.Biochar dosage and flow rate affect the dynamic adsorption removal process of fixed-bed columns.Thomas model,Yoon-Nelson model,Clark model and BDST model all well simulate and predict the column experimental data.The results indicate great application prospect of biochar in large-scale AP removal.

biocharacetaminophenadsorptionfixed-bed

张彤宇、康静静、严乙洋、王雨、王号、李宵慧、陈晔

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南京师范大学海洋科学与工程学院,江苏 南京 210023

生物炭 对乙酰氨基酚 吸附 固定床

国家自然科学基金项目江苏省自然科学基金项目江苏省高校自然科学基金项目南京师范大学海洋科学与工程学院大学生创新创业计划项目

42107061BK2021057121KJB170023

2024

南京师范大学学报(工程技术版)
南京师范大学

南京师范大学学报(工程技术版)

影响因子:0.313
ISSN:1672-1292
年,卷(期):2024.24(1)
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