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棕壤不同粒径组分对阿特拉津吸附-解吸作用的影响

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采用批平衡实验,研究阿特拉津在棕壤不同粒径组分上的吸附-解吸行为.结果表明,阿特拉津在不同粒径组分上的Kf值从大到小顺序为:5~10 μm≈2~5 μm≈<2μm>10~50 μm>50~250 μm.其中,当粒径为<2,2~5和5~10 μm,其吸附作用与土壤颗粒的有机质含量和游离氧化铁铝的量无明显相关性,这种现象可能与土壤有机质的组分、结构特征及有机质与矿物结合的方式有关.阿特拉津在不同粒径组分上的解吸作用均存在不同程度的滞后作用,且均为正滞后现象.其中,尤以在5~10μm粒径上的滞后现象最明显.
Effect of Different Particle-size Separates of Brown Soil on the Sorption and Desorption of Atrazine
A series of batch experiments were carried out to determine the adsorption and desorption of atrazine by brown soil different particle-size separates. The results showed that the rankings of the adsorption capacities (K_f) of atrazine by different particle-size separates of 5 - 10 μm≈2 - 5 μm≈<2 μm>10 - 50 μm>50 -250 μm, respectively. The values of K_f of different particle-size of brown soil had no significant correlation with the content of organic matter content and DCB extractable Fe and Al. It was possible that adsorption of atrazine was impacted by the component of organic matter,structural character and binding mode of organic matter and mineral. Hysteresis observed in different particle-size separates of brown soils, and all were positive hysteresis. It was the most obvious in 5 -10 μm particle-size.

brownparticle-size separatesatrazinesorption-desorptionhysteresis

高敏苓、宋文华、依艳丽

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天津工业大学环境与化学工程学院,天津300387

沈阳农业大学土地与环境学院,辽宁沈阳110161

棕壤 粒径组分 阿特拉津 吸附-解吸 滞后性

国家重点基础研究发展规划(973计划)

2008CB417202

2009

南开大学学报(自然科学版)
南开大学

南开大学学报(自然科学版)

CSTPCDCSCD北大核心
影响因子:0.284
ISSN:0465-7942
年,卷(期):2009.42(6)
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