首页|纳米伊/蒙粘土对铅和镉污染土壤钝化效果研究

纳米伊/蒙粘土对铅和镉污染土壤钝化效果研究

扫码查看
本文选取矿区周边铅和镉复合重金属污染的农田土壤,添加纳米伊/蒙粘土,进行了农田铅和镉钝化试验,评价纳米伊/蒙粘土降低溶液铅和镉浓度以及降低土壤铅和镉有效态含量的效果.结果表明,纳米伊/蒙粘土对溶液铅和镉离子吸附过程遵守Langmuir等温模型,其饱和吸附量分别是263.16mg·kg-1和13.32 mg·kg-1.与对照相比,添加1%纳米伊/蒙粘土,醋酸提取的土壤铅和镉有效态浓度分别下降了 34.07%和34.04%;196天后分别下降23.74%和45.86%,说明纳米伊/蒙粘土能一定程度降低土壤铅和镉有效态浓度,形态分析表明纳米伊/蒙粘土可同时促进土壤铅和镉从不稳定态向稳定态转化.
Morphological influence on immobilization of heavy metal contaminated soils by Nano-Il-lite/Smectite Clay
Nano-Illite/smectite clay has been used to remediate soils contaminated by heavy metals.In this study we evaluated the immobilization of heavy metal in soils by Nano-Illite/smectite clay,based on the adsorption of heavy metals and leaching toxicity especially the formation in farmland soil Pb-Zn polution.The result suggested that Nano-Illite/smectite clay had a capacaity of adsorption on Pb,Cd in the simulated conditions.The adsorption of heavy metal was suitable for Langmuir isotherm adsorption model.Applications of Nano-Illite/smectite clay dramatically decreased the leachability of heavy metal,the reduction of Cd,Pb concentrations in ethylic acid extraction was34.04%,34.07%compared controlled in the mass ratio of 1%(Nano-Illite/smectite clay:Soil).The experiment of chemical stabilization remediation of heavy metals showed that compared with CK the percent reduction of Pb,Cd concentrations in MgC12 ex-traction was 23.74%,45.86%after196th day,and pH increased by 0.1,with increasing of other formaiton in the soil.It was suggested that the Nano-Illite/smectite clay could transform from instable to stable forms.

Heavy metalsSoilNano-Illite/smectite clayForms

车轩、金晓丹、杨勤、庞雪蕾

展开 >

广西壮族自治区环境保护科学研究院,广西南宁 530022

河北省生态环境监测中心,河北石家庄 050000

河北科技大学,河北石家庄 050000

重金属 土壤 纳米/伊蒙粘土 形态

河北省自然科学基金

B2019208282

2024

环境与发展
内蒙古自治区环境科学研究院,内蒙古环境检测中心站

环境与发展

影响因子:0.326
ISSN:1007-0370
年,卷(期):2024.36(2)
  • 16