环境与发展2024,Vol.36Issue(6) :36-40.DOI:10.16647/j.cnki.cn15-1369/X.2024.06.007

某联合站土壤中石油类不确定度评定

Uncertainty evaluation of determination of petroleum in soil by infrared spectro-photometry

杨丹丹 杨琴 周娟 朱恒 席佳欣
环境与发展2024,Vol.36Issue(6) :36-40.DOI:10.16647/j.cnki.cn15-1369/X.2024.06.007

某联合站土壤中石油类不确定度评定

Uncertainty evaluation of determination of petroleum in soil by infrared spectro-photometry

杨丹丹 1杨琴 1周娟 1朱恒 1席佳欣1
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作者信息

  • 1. 长庆油田分公司油气工艺研究院,陕西 西安 710018;低渗透油气田勘探开发国家工程实验室,陕西 西安 710018
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摘要

分析探讨了红外分光光度法测定土壤中石油类含量不确定度的影响因素,并对其不确定度分量进行了评定,计算得到合成相对标准不确定度值为0.036,其中由待测液浓度引入的相对合成不确定度为0.033;最大的不确定度分量是标准曲线拟合引入的不确定度,分量值为0.029.测定土壤中石油类结果为57.3±4.12mg/kg;k=2(置信水平约为95%).

Abstract

The factors affecting the uncertainty of determination of petroleum content in soil by infrared spectro-photometry were analyzed in this study.And the uncertainty components were also assessed.The value of synthesis rel-ative uncertainty was 0.036,and the relative combined uncertainty caused by the digestion of the test fluid concentra-tion was 0.033;the largest component of uncertainty was produced by fitting the standard curve and the value was 0.029.The measurement result was X=57.3±4.12mg/kg,(k=2)(95%confidence level).

关键词

不确定度/土壤/石油类/红外分光光度法

Key words

Uncertainty/Soil/Petroleum/Infrared spectro-photometry

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出版年

2024
环境与发展
内蒙古自治区环境科学研究院,内蒙古环境检测中心站

环境与发展

影响因子:0.326
ISSN:1007-0370
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