Wear-resistant Ag-MAX phase 3D interpenetrating-phase composites:Processing,structure,and properties

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外文摘要：Electrical contact materials are generally Ag-or Cu-based composites and play a critical role in ensuring the reliability and efficiency of electrical equipments and electronic instruments.The MAX(M is an early transition metal,A is an element from Ⅲ orⅣ main groups,and X is carbon or/and nitrogen)phase ceramics display a unique combination of properties and may serve as an ideal reinforcement phase for electrical contact materials.The biological materials evolved in nature generally exhibit three-dimensional(3D)interpenetrating-phase architectures,which may offer useful inspiration for the architectural design of electrical contact materials.Here,a series of bi-continuous Ag-Ti3SiC2 MAX phase composites with high ceramic contents exceeding 50 vol.％and having micron-and ultrafine-scaled 3D interpenetrating-phase architectures,wherein both constituents were continuous and mutually interspersed,were exploited by pressureless infiltration of Ag melt into partially sintered Ti3SiC2 scaffolds.The mechanical and electrical properties as well as the friction and wear performance of the composites were investigated and revealed to be closely dependent on the ceramic contents and characteristic structural dimensions.The composites exhibited a good combination of properties with high hardness over 2.3 GPa,high flexural strength exceeding 530 MPa,decent fracture toughness over 10 MPa·m1/2,and good wear resistance with low wear rate at an order of 10-5 mm3/(N·m),which were much superior compared to the counterparts made by powder metallurgy methods.In particular,the hardness,electrical conductivity,strength,and fracture toughness of the composites demonstrated a simultaneous improvement as the structure was refined from micron-to ultrafine-scales at equivalent ceramic contents.The good combination of properties along with the facile processing route makes the Ag-Ti3SiC2 3D interpenetrating-phase composites appealing for electrical contact applications.

外文关键词：

three-dimensional(3D)interpenetrating-phase architectureAg-MAX(M=early transition metal,A=element from Ⅲ or Ⅳmain groups,and X=carbon or/and nitrogen)phase compositesmelt infiltrationelectrical contact materialsmechanical propertieswear resistance

作者：

Yu Guo、Xi Xie、Zengqian Liu、Longchao Zhuo、Jian Zhang、Shaogang Wang、Qiqiang Duan、Qing Jia、Dake Xu、Weihai Xue、Deli Duan、Filippo Berto、Zhefeng Zhang、Rui Yang

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作者单位：

Shi-Changxu Innovation Center for Advanced Materials,Institute of Metal Research,Chinese Academy of Sciences,Shenyang 110016,China

School of Materials Science and Engineering,University of Science and Technology of China,Hefei 230026,China

School of Materials Science and Engineering,Xi'an University of Technology,Xi'an 710048,China

Electrobiomaterials Institute,Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education),Northeastern University,Shenyang 110819,China

Shenyang National Laboratory for Materials Science,Institute of Metal Research,Chinese Academy of Sciences,Shenyang 110016,China

Department of Chemical Engineering,Materials and Environment,Sapienza University of Rome,Roma 00185,Italy

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基金：

National Key R&D Program of ChinaNational Natural Science Foundation of ChinaKC Wong Education FoundationLiaoning Revitalization Talents ProgramYouth Innovation Promotion Association CAS

项目编号：

2020YFA071040452173269GJTD-2020-092019191

出版年：

2024

DOI：

10.1007/s12274-023-6015-1

纳米研究(英文版)

CSTPCD

ISSN：

年,卷(期)：2024.17(2)

参考文献量69