Metal organic frameworks-based cathode materials for advanced Li-S batteries:A comprehensive review

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外文摘要：Li-S batteries(LSBs)have been considering as new and promising energy storage systems because of the high theoretical energy density and low price.Nevertheless,their practical application is inhibited by several factors,including poor electrical conductivity of electrode materials,greatly volumetric variation,as well as the polysulfide formation upon the cycling.To address these problems,it is imperative to develop and design effective and suitable sulfur host anode materials.Metal organic frameworks(MOFs)-based cathode materials,possessing their good conductivity and easy morphology design,have been extensively studied and exhibited enormously potential in LSBs.In this review,a comprehensive overview of MOFs-based sulfur host materials is provided,including their electrochemical reaction mechanisms,related evaluation parameters,and their performances used in LSBs in the past few years.In particular,the recent advances using in-situ characterization technologies for investigating the electrochemical reaction mechanism in LSBs are presented and highlighted.Additionally,the challenges and prospects associated with future research on MOF-related sulfur host materials are discussed.It is anticipated to offer the guidance for the identification of suitable MOFs-based sulfur cathode materials for high-performance LSBs,thereby contributing for the achievement of a sustainable and renewable society.

外文关键词：

lithium metal anodesulfur cathodemetal organic frameworkshostenergy densityin-situ characterization

作者：

Zhengkun Xie、Boyong Cao、Xiyan Yue、Ruixue Wang、Ziqian Xue、Jiajia Wang、Guoqing Guan、Weihua Chen

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作者单位：

College of Chemistry,Zhengzhou University,Zhengzhou 450001,China

School of Ecology and Environment,Zhengzhou University,Zhengzhou 450001,China

Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education),Nankai University,Tianjin 300071,China

School of Materials Science and Engineering,Henan Polytechnic University,Jiaozuo 454003,China

Institute for Integrated Cell-Material Sciences(iCeMS),Kyoto University,Sakyo-ku,Kyoto 606-8501,Japan

Laboratory of Energy Conversion Engineering,Institute of Regional Innovation,Hirosaki University,3 Bunkyo-cho,Hirosaki,Aomori 036-8561,Japan

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基金：

National Natural Science Foundation of ChinaNational Natural Science Foundation of ChinaKey Research and Development Program of Henan ProvinceJoint Fund of Scientific and Technological Research,Development Program of Henan ProvinceChunhui Plan Cooperative Research Project Foundation of Ministry of Education of China

项目编号：

2227912122209153231111241400222301420009202200713

出版年：

2024

DOI：

10.1007/s12274-024-6481-0

纳米研究(英文版)

CSTPCD

ISSN：

年,卷(期)：2024.17(4)

参考文献量206