首页|三元锂不燃电解液的开发

三元锂不燃电解液的开发

Development of Non-Combustible Ternary Lithium Electrolyte

扫码查看
锂离子电池被广泛应用于动力电池、储能和电子消费品等领域.在动力电池领域,三元锂和磷酸铁锂是2种常用的锂离子电池正极材料.三元锂材料具有放电电压高、输出功率大和能量密度高的特点,一直被用于快充和长续航车型.然而由于其分解温度低,化学反应更加剧烈,导致电解液迅速燃烧引发连锁反应,从而使三元锂电池比磷酸铁锂电池更容易引起安全事故.基于低共熔溶剂的开发策略,开发了一款完全不燃的三元锂电解液.三元锂不燃电解液以N,N-二甲基三氟乙酰胺(DTA)和乙氧基五氟环三磷腈(PFPN)作为溶剂(物质的量均为2 mol),以1mol的双氟磺酰亚胺锂(LiFSI)为锂盐,以2%(质量分数)碳酸亚乙烯酯(VC)和0.5%(质量分数)二氟磷酸锂(LiPO2F2)为添加剂,在0.5C充放电倍率的条件下,该不燃电解液在25 ℃的常温循环和45 ℃的高温循环都超过了 500次,容量保持率大于80%,具有进一步开发研究的商业价值.
Lithium-ion batteries are widely used in power batteries,energy storage and consumer electronics.In the field of power bat-teries,ternary lithium and lithium iron phosphate are two commonly used cathode materials for lithium-ion batteries.Ternary lithium materials have the characteristics of high discharge voltage,high output power and high energy density,and have been used in fast charging and long-range models.However,due to its low decomposition temperature,the chemical reaction is more violent,causing the electrolyte to burn rapidly and trigger a chain reaction,making ternary lithium batteries more likely to cause safety accidents than lithium iron phosphate batteries.In view of this,it developed a completely non-combustible ternary lithium electrolyte based on the de-velopment strategy of deep eutectic solvents.The ternary lithium non-combustible electrolyte used N,N-dimethyltrifluoroacetamide(DTA)and ethoxypentafluorocyclotriphosphazene(PFPN)as a solvent(molar is 2 mol),and 1 mol bisfluoride lithium sulfonylimide(LiFSI)is a lithium salt with 2%vinylene carbonate(VC)and 0.5%lithium difluorophosphate(LiPO2F2)as the additives.Under the condition of 0.5C charge and discharge rate,the non-combustible electrolyte has been cycled at 25 ℃ and 45 ℃ for more than 500 times,with a capacity retention rate of more than 80%,which has the commercial value for further development and research.

ternary lithiumnon-combustible electrolytedeep eutectic solvent

何天贤、刘文杰、麦明珠、戚金凤、雷源春

展开 >

广州科技职业技术大学,广东 广州 510550

三元锂 不燃电解液 低共熔溶剂

2024

现代车用动力
中国一汽无锡油泵油嘴研究所

现代车用动力

影响因子:0.153
ISSN:1671-5446
年,卷(期):2024.(4)